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Nucleophilicity of N-propargylanilines in the coordination to zinc tetraphenylporphyrin in chloroform

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Abstract

Thermodynamic parameters (ΔG 0 and ΔS 0) of the isoenthalpic (except for 4-halo derivatives) coordination of (tetraphenylporphyrinato)zinc(II) with anilines in chloroform at 273–313 K linearly correlate with the shift of their electronic absorption maxima in the reaction with anilines, as well as with the logarithms of the stability constants of the complexes, pK a values of the ligands in water, and substituent constants σ+. The 2: 1 complex of (tetraphenylporphyrinato)zinc(II) with p-phenylenediamine was characterized by the X-ray diffraction data

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Authors and Affiliations

  1. Petrozavodsk State University, pr. Lenina 33, Petrozavodsk, 185910, Russia

    V. P. Andreev, P. S. Sobolev & D. O. Zaitsev

  2. Bekturov Institute of Chemical Sciences, ul. Valikhanova 106, Almaty, 050010, Kazakhstan

    S. A. Vizer & K. B. Erzhanov

  3. Faculty of Chemistry, Moscow State University, Leninskie gory 1, Moscow, 119991, Russia

    V. A. Tafeenko

Authors
  1. V. P. Andreev
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  2. P. S. Sobolev
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  3. D. O. Zaitsev
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  4. S. A. Vizer
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  5. K. B. Erzhanov
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  6. V. A. Tafeenko
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Correspondence to V. P. Andreev.

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Original Russian Text © V.P. Andreev, P.S. Sobolev, D.O. Zaitsev, S.A. Vizer, K.B. Erzhanov, V.A. Tafeenko, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 8, pp. 1378–1387.

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Andreev, V.P., Sobolev, P.S., Zaitsev, D.O. et al. Nucleophilicity of N-propargylanilines in the coordination to zinc tetraphenylporphyrin in chloroform. Russ J Gen Chem 84, 1599–1607 (2014). https://doi.org/10.1134/S1070363214080271

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  • DOI: https://doi.org/10.1134/S1070363214080271

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