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Reactions of α-nitroacrylates with thiophenols

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Abstract

Reactions of α-nitroacrylates with aromatic thiols like 4-methyl- and 4-chlorothiophenols afford a series of new 3-arylsulfanyl-2-nitropropanoates. The latter were isolated as diastereomerically pure substances or mixtures of two diastereomers. Structures of the obtained S-adducts were confirmed by IR, 1H and 13C-{1H} NMR spectroscopy using HMQC and HMBC experiments.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    R. I. Baichurin, L. V. Baichurina, N. I. Aboskalova, E. V. Trukhin & V. M. Berestovitskaya

Authors
  1. R. I. Baichurin
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  2. L. V. Baichurina
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  3. N. I. Aboskalova
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  4. E. V. Trukhin
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  5. V. M. Berestovitskaya
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Correspondence to R. I. Baichurin.

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Original Russian Text © R.I. Baichurin, L.V. Baichurina, N.I. Aboskalova, E.V. Trukhin, V.M. Berestovitskaya, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 7, pp. 1079–1088.

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Baichurin, R.I., Baichurina, L.V., Aboskalova, N.I. et al. Reactions of α-nitroacrylates with thiophenols. Russ J Gen Chem 84, 1277–1286 (2014). https://doi.org/10.1134/S1070363214070056

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  • DOI: https://doi.org/10.1134/S1070363214070056

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