Skip to main content
SpringerLink
Log in

Modification of the silica particles surface with perfluoroalkylmethyloxiranes

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Silica particles have been prepared via the sol-gel process in the presence of perfluoropropyl- and perfluorobutylmethyloxiranes. Nanoparticles are formed in the presence of acidic catalyst. Under conditions of basic catalysis the attack of silanol group (formed in situ via hydrolysis of tetraethoxysilane) on the oxirane ring leads likely to the Si-O-C bond formation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shabanova, N.A. and Sarkisov, P.D., Osnovy zol’-gel’ tekhnologii nanodispersnogo kremnezema (Fundamentals of Sol-Gel Technology of Nanosized Silica), Moscow: IKC “Akademkniga,” 2004.

    Google Scholar 

  2. Oh, E.O., Gupta, R.K., and Whang, C.M., J. Sol-Gel Sci. Techn., 2003, vol. 28, p. 279.

    Article  CAS  Google Scholar 

  3. Tripathi, V.S., Kandimalla, V.B., and Ju, H., Sensor. Actuat. B-Chem., 2006, vol. 114, p. 1071. DOI: 10.1016/j.snb., 2005.07.037.

    Article  CAS  Google Scholar 

  4. Etienne, P., Denape, J., Paris, J.Y., Phalippou, J., and Sempere, R., J. Sol-Gel Sci. Techn., 1996, vol. 6, p. 287.

    Article  CAS  Google Scholar 

  5. Hu, R.-G., Zhang, S., Bu, J.-F., Lin, C.-J., and Song, G.-L., Prog. Org. Coat., 2012, vol. 73, p. 129. DOI: 10.1016/j.porgcoat., 2011.10.011.

    Article  CAS  Google Scholar 

  6. Malinovskii, M.S., Okisi olefinov i ikh proizvodnye (Olefin Oxides and Their Derivatives), Moscow: Goskhimizdat, 1961.

    Google Scholar 

  7. Gorbunova, T.I., Zapevalov, A.Ya., and Saloutin, V.I., Russ. J. Org. Chem., 1998, vol. 34, no. 3, p. 360.

    CAS  Google Scholar 

  8. Voronkov, M.G., Yuzhelevskii, Yu.A., and Mileshkevich, V.P., Russ. Chem. Rev., 1975, vol. 44, no. 4, p. 355.

    Article  Google Scholar 

  9. RF Patent 2438973, 2007; Byull. Izobret., 2012, no. 1.

  10. Contado, C., Ravani, L., and Passarella, M., Anal. Chim. Acta, 2013, vol. 788, p. 183. DOI: 10.1016/j.aca.2013.05.056.

    Article  CAS  Google Scholar 

  11. Chen, M.Q., Chen, H.Y., Shu, D., Li, A.J., and Finlow, D.E., J. Power Sources, 2008, vol. 181, p. 161. DOI: 10.1016/j.jpowsour.2008.03.009.

    Article  CAS  Google Scholar 

  12. Costa, T.M.H., Gallas, M.R., Benvenutti, E.V., and Da Jornada, J.A.H., J. Non-Cryst. Solids, 1997, vol. 220, p. 195. DOI: 10.1016/S0022-3093(97)00236-6.

    Article  CAS  Google Scholar 

  13. Fomenko, O.E. and Ressner, F., Sorbts. Khromatogr. Proces., 2009, vol. 9, no. 5, p. 633.

    Google Scholar 

  14. Fisher, C.E., Mink, J., Hajba, L., Bacsik, Z., Németh, C., Mihály, J., Raith, A., and Cokoja, M., Kühn, F.E., Vib. Spectrosc., 2013, vol. 66, p. 104. DOI: 10.1016/j.vibspec.2013.01.012.

    Article  Google Scholar 

  15. Li, X., Yin, X., Zhang, L., and He, S., J. Non-Cryst. Solids, 2008, vol. 354, p. 3254. DOI: 10.1016/j.jnoncrysol.2008.02.016.

    Article  CAS  Google Scholar 

  16. Ghosh, T.B., Nandi, K.C., Acharya, H.N., and Mukherjee, D., Mater. Lett., 1991, vol. 12, p. 175. DOI: 10.1016/0167-577X(91)90169-7.

    Article  CAS  Google Scholar 

  17. Khabashesku, V.N., Russ. Chem. Rev., 2011, vol. 80, no. 8, p. 705. DOI: 10.1070/RC2011v080n-08ABEH004232.

    Article  CAS  Google Scholar 

  18. Wang, B., Li, J., Zhang, J., Li, H., Chen, P., Gu, Q., and Wang, Z., Carbohyd. Polym., 2013, vol. 95, p. 100. DOI: 10.1016/j.carbpol.2013.02.055.

    Article  CAS  Google Scholar 

  19. Pacard, E., Brook, M.A., Ragheb, A.M., Pichot, C., and Chaix, C., Colloid. Surface (B), 2006, vol. 47, p. 176. DOI: 10.1016/j.colsurfb.2005.12.008.

    CAS  Google Scholar 

  20. Bucatariu, F., Simon, F., Bellmann, C., Fundueanu, G., and Dragan, E.S., Colloid. Surface (A), 2012, vol. 399, p. 71. DOI: 10.1016/j.colsurfa.2012.02.030.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 22/Akademicheskaya 20, Yekaterinburg, 620990, Russia

    T. I. Gorbunova, A. Ya. Zapevalov & V. I. Saloutin

  2. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    I. V. Beketov

  3. Institute of Physics of Metals, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    V. S. Gaviko

  4. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    E. G. Vovkotrub

Authors
  1. T. I. Gorbunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Ya. Zapevalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Beketov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. S. Gaviko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. G. Vovkotrub
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. I. Saloutin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. I. Gorbunova.

Additional information

Original Russian Text © T.I. Gorbunova, A.Ya. Zapevalov, I.V. Beketov, V.S. Gaviko, E.G. Vovkotrub, V.I. Saloutin, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 7, pp. 1067–1074.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorbunova, T.I., Zapevalov, A.Y., Beketov, I.V. et al. Modification of the silica particles surface with perfluoroalkylmethyloxiranes. Russ J Gen Chem 84, 1265–1272 (2014). https://doi.org/10.1134/S1070363214070032

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214070032

Keywords

Search

Navigation