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Spectrophotometric study of acid-base and complexing properties of 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin in acetonitrile

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Abstract

Acid-base and complexing properties of 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin have been studied by means of spectrophotometry in the acetonitrile/1,8-diazabicyclo[5.4.0]undec-7-ene, acetonitrile/perchloric acid, and acetonitrile/zinc acetate media. The ionization constants and concentration ranges of ionized forms existence have been determined, spectral parameters of the studied porphyrin and its zinc complex have been elucidated, and kinetic parameters of the zinc complex formation have been analyzed.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. B. Ivanova, N. V. Chizhova & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    Dao Tkhe Nam

Authors
  1. Yu. B. Ivanova
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  2. Dao Tkhe Nam
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  3. N. V. Chizhova
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  4. N. Zh. Mamardashvili
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Correspondence to Yu. B. Ivanova.

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Original Russian Text © Yu.B. Ivanova, Dao Tkhe Nam, N. V. Chizhova, N.Zh. Mamardashvili, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 1030–1034.

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Ivanova, Y.B., Nam, D.T., Chizhova, N.V. et al. Spectrophotometric study of acid-base and complexing properties of 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin in acetonitrile. Russ J Gen Chem 84, 1207–1211 (2014). https://doi.org/10.1134/S1070363214060255

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  • DOI: https://doi.org/10.1134/S1070363214060255

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