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Factors affecting photoisomerization of 4-styrylpyridine

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Abstract

Photoisomerization of 4-styrylpyridine at different irradiation wavelengths (λ 365 and 254 nm) and in different solvents was studied by UV and 1H NMR spectroscopy. A procedure for recording the UV spectra of 4-styrylpyridine dissolved in liquid crystalline films freely suspended within a frame. The results of quantum-chemical calculations of the geometry and UV spectra of 4-styrylpyridine isomers are presented.

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Authors and Affiliations

  1. Zavoiskii Kazan Physical Technical Institute, Kazan Research Center, Russian Academy of Sciences, Sibirskii trakt 10/7, Kazan, Tatarstan, 420029, Russia

    L. G. Gafiyatullin, L. I. Savostina, O. I. Gnezdilov, O. A. Turanova, I. V. Ovchinnikov & A. N. Turanov

Authors
  1. L. G. Gafiyatullin
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  2. L. I. Savostina
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  3. O. I. Gnezdilov
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  4. O. A. Turanova
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  5. I. V. Ovchinnikov
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  6. A. N. Turanov
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Corresponding author

Correspondence to A. N. Turanov.

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Original Russian Text © L.G. Gafiyatullin, L.I. Savostina, O.I. Gnezdilov, O.A. Turanova, I.V. Ovchinnikov, A.N. Turanov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 966–972.

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Gafiyatullin, L.G., Savostina, L.I., Gnezdilov, O.I. et al. Factors affecting photoisomerization of 4-styrylpyridine. Russ J Gen Chem 84, 1146–1152 (2014). https://doi.org/10.1134/S1070363214060164

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  • DOI: https://doi.org/10.1134/S1070363214060164

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