Abstract
The gas-chromatographic retention indices of the products of 1,1-dimethylhydrazine transformations in the presence of sulfur allows one to confirm and, in ceratin cases, make more exact the results of their gas chromatography-mass spectrometry identification. Features of identification of new compounds, including 1,1-dimethyl-2-thioxohydrazine are discussed.
Similar content being viewed by others
References
Buryak, A.K., Davidovskii, N.V., and Ul’yanov, A.V., Khromatografiya na blago Rossii (Chromatography for the Sake of Russia), Moscow: Granitsa, 2007, p. 81.
Ioffe, B.V., Kuznetsov, M.A., and Potekhin, A.A., Khimiya organicheskikh proizvodnykh gidrazina (Chemistry of Organic Hydrazine Derivatives), Leningrad: Khimiya, 1979.
Buryak, A.K., Tataurova, O.G., and Ul’yanov, A.V., Mass-spektrometriya, 2004, vol. 1, no. 2, p. 147.
Golub, S.L., Lugovskaya, I.G., Anufrieva, S.I., Dubinchuk, V.T., Ul’yanov, A.V., and Buryak, A.K., Sorbts. Khromatogr. Processy, 2006, vol. 6, no. 5, p. 855.
Smolenkov, A.D., Rodin, I.A., Shpak, A.V., and Shpigun, O.A., Int. J. Environ. Anal. Chem., 2007, vol. 87, no. 5, p. 351.
Rodin, I.A., Moskvin, D.N., Smolenkov, A.D., and Shpigun, O.A., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 6, p. 911.
Zatirakha, A.V., Smolenkov, A.D., Elfimova, Ya.A., and Shpigun, O.A., Sorbts. Khromatogr. Processy, 2009, vol. 9, no. 4, p. 545.
Zatirakha, A.V., Smolenkov, A.D., and Shpigun, O.A., Zav. Lab. Diagn. Mater., 2009, vol. 75, no. 4, p. 15.
Rodin, I.A., Anan’eva, I.A., Smolenkov, A.D., and Shpigun, O.A., Mass-spektrometriya, 2009, vol. 6, no. 4, p. 302.
Golub, S.L., Lugovskaya, S.I., Anufrieva, V.G., Dubinchuk, V.T., Ul’yanov, A.V., and Buryak, A.K., Sorbts. Khromatogr. Processy, 2006, vol. 6, no. 5, p. 748.
Zenkevich, I.G, 100 let khromatografii (100 Years of Chromatography), Rudenko, B.A., Ed., Moscow: Nauka, 2003, p. 311.
Bruce, R.B., Open Access Dissertations and Theses, paper 3339. http://digitalcommons.mcmaster.ca/opendissertations/3339.
Taylor, P., Durham Theses, Durham Univ., 1989. http://etheses.dur.ac.uk/6482/.
Chivers, T., A Guide to Chalcogen-Nitrogen Chemistry, Singapore: World Sci. Publ., 2005.
Darwent, B. de B., Bond Dissociation Energies in Simple Molecules, Washington: Natl. Stand. Ref. Data Ser., 1970.
Zhang, Y. and Ho, C.-T., J. Agric. Food Chem., 1989, vol. 37, no. 4, p. 1016.
Zhang, Y. and Ho, C.-T., J. Agric. Food Chem., 1991, vol. 39, no. 3, p. 760.
Tai, C.-Y. and Ho, C.-T., J. Agric. Food Chem., 1998, vol. 46, no. 6, p. 2260.
Kubec, R., Drhova, V., and Velisek, J., J. Agric. Food Chem., 1999, vol. 47, no. 3, p. 1132.
Parker, J.K., Hassell, G.M.E., Mottram, D.S., and Guy, R.C.E., J. Agric. Food Chem., 2000, vol. 48, no. 8, p. 3497.
Shivashankar, S., Riy, T.K., and Moorthy, P.N.K., Chem. Bull. “Politechnika” Univ. Timisoara, Romania, 2012, vol. 57(71), no. 1, p. 1.
NIST/EPA/NIH Mass Spectral Library and Search Software (NIST11), NIST Standard Reference Database, Gaithersburg, MD: National Institute of Standards and Technology, 2011, no. 69; http:webbook.nist.gov
Clark, P.D., Hyne, J.B., and Lesage, K.L., Alberta Sulfur Res. Quart. Bull., 1984, vol. 20, p. 1.
Gizftullina, I.H., Fakhriev, A.M., Mazgarov, A.M., and Fazliev, D.F., Zh. Prikl. Khim., 1986, vol. 59, no. 1, p. 111.
Deryagina, E.N., Kozlov, I.A., Vershal’, V.V., and Babkin, V.A., Zh. Obshch. Khim., 1996, vol. 66, no. 8, p. 1279.
Organic Chemicals Product Information. Mercaptans and Derivative Chemistry, Philadelphia, Pa.: Arkema, 2001. http:www.arkemagroup.com.
Yamada, S., Wang, D., Li, S., Nishikawa, M., Qian, E.W., Ishikara, A., and Kabe, T., Chem. Commun., 2003, no. 7, p. 842.
Russavskaya, N.V., Grabel’nykh, V.A., Levanova, E.P., Sukhomazova, E.N., and Deryagina, E.N., Russ. J. Org. Chem., 2002, vol. 38, no. 10, p. 1445.
Taniguchi, N., Synlett, 2007, no. 12, p. 1917.
Middleton, W.H., J. Am. Chem. Soc., 1966, vol. 88, no. 16, p. 3842.
Tresoldi, G., Bruno, G., Crucitti, F., and Piraino, P., J. Organomet. Chem., 1983, vol. 252, no. 7, p. 381.
Tresoldi, G., Bruno, G., Piraino, P., Faraone, G., and Bombieri, G., J. Organomet. Chem., 1984, vol. 265, no. 22, p. 311.
Herberhold, M. and Hill, A.F., J. Organomet. Chem., 1986, vol. 315, no. 12, p. 105.
Gieren, A., Ruiz-Perez, C., Hubner, T., Hernerhold, M., and Hill, A.F., J. Chem. Soc. Dalton Trans., 1988, no. 6, p. 1693.
Roesky, H.W., Emmert, R., Isenberg, W., Schmidt, M., and Sheldrick, G.M., J. Chem. Soc. Dalton Trans., 1983, no. 5, p. 183.
Roesky, H.M., Emmert, R., Clegg, W., Isenberg, W., and Sheldrick, G.M., Angew. Chem., 1981, vol. 93, no. 4, p. 623.
Zenkevich I.G., Zh. Anal. Chem., 1984, vol. 39, no. 7, p. 1297.
Zenkevich, I.G. and Ioffe, B.V., J. Chromatogr., 1988, vol. 439, no. 1, p. 185.
Stolyarov, B.V., Savinov, I.M., Vitenberg, A.G., Kartsova. L.A., Zenkevich, I.G., Kalmanovskii, V.I., and Kalambet, Yu.A., Prakticheskaya gazovaya i zhidkostnaya khromatografiya (Practical Gas and Liquid Chromatography), St. Petersburg: Sankt-Peterb. Gos. Univ., 2002.
Savel’eva, E.I., Zenkevich, I.G., and Radilov, A.S., J. Analyt. Chem., 2003, vol. 58, no. 2, p. 114.
Zenkevich, I.G., Zh. Org. Khim., 1992, vol. 28, no. 9, p. 1927.
Lebedev, A.T., Mass-spektrometriya v organicheskoi khimii (Mass Spectrometry in Organic Chemistry), Moscow: Binom, 2003.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.G. Zenkevich, A.V. Ul’yanov, S.L. Golub, A.K. Buryak, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 923–931.
Rights and permissions
About this article
Cite this article
Zenkevich, I.G., Ul’yanov, A.V., Golub, S.L. et al. Chromatographic component of identification of the transformation products of 1,1-dimethylhydrazine in the presence of sulfur. Russ J Gen Chem 84, 1106–1114 (2014). https://doi.org/10.1134/S1070363214060097
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363214060097