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Oxidative polymerization of p-phenylenediamine

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Abstract

Oxidative polymerization of p-phenylenediamine in a hydrochloric acid solution yields not a polyquinoxaline polymer as described in the literature but a modified poly(1,4-benzoquinonediimine-N,N′-diyl-1,4-phenylene) analogous to polyaniline known as pernigraniline. A new scheme of oxidative polymerization of p-phenylenediamine was suggested.

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Authors and Affiliations

  1. Yerevan State University, ul. A. Manukyana 1, Yerevan, 375025, Armenia

    A. A. Durgaryan, R. A. Arakelyan & N. A. Durgaryan

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  1. A. A. Durgaryan
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  2. R. A. Arakelyan
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  3. N. A. Durgaryan
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Correspondence to A. A. Durgaryan.

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Original Russian Text © A.A. Durgaryan, R.A. Arakelyan, N.A. Durgaryan, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 912–917.

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Durgaryan, A.A., Arakelyan, R.A. & Durgaryan, N.A. Oxidative polymerization of p-phenylenediamine. Russ J Gen Chem 84, 1095–1100 (2014). https://doi.org/10.1134/S1070363214060073

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  • DOI: https://doi.org/10.1134/S1070363214060073

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