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Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: V. Synthesis of 4-bromophthalonitrile

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Abstract

Oxidative ammonolysis of 4-bromo-o-xylene on a V-Sb-Bi-Zr/γ-Al2O3 catalyst gives 74.82 mol % of 4-bromophthalonitrile at a high conversion of the starting xylene in a one-cycle process. The process with recirculation results in decreased number of by-products and contribution of deep oxidation and increased selectivity in 4-bromophthalonitrile up to 95.42–96.58%.

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References

  1. Bagirzade, G.A., Russ. J. Gen. Chem., 2014, vol. 84, no. 6, p. 1075.

    Google Scholar 

  2. Bagirzade, G.A., Russ. J. Gen. Chem., 2010, vol. 80, no. 8, p. 1672.

    Article  CAS  Google Scholar 

  3. Bagirzade, G.A., Russ. J. Gen. Chem., 2010, vol. 80, no. 9, p. 1779.

    Article  CAS  Google Scholar 

  4. Bagirzade, G.A., Russ. J. Gen. Chem., 2013, vol. 83, no. 3, p. 492.

    Article  CAS  Google Scholar 

  5. Rizaev, R.G., Magerramova, Z.Yu., Sheinin, V.E., Bagirzade, G.A., Guseinov, I.A., and Geidarly, N.I., Azerb. Khim. Zh., 2005, no. 4, p. 19.

    Google Scholar 

  6. Rizaev, R.G., Sheinin, V.E., Magerramova, Z.Yu., Suleimanov, T.E., Bagirzade, G.A., and Guseinov, I.A., Mater. nauchno-tekhn. konf. v oblasti neorganicheskoi i fizicheskoi himii, posvyashchennoi 60-letiyu institute (Proc. Scientific and Technical Conf. on Inorganic and Physical Chemistry Dedicated to the 60th Anniversary of the Institute), Baku: Inst. Inorg. Phis. Khim. Azerb. Akad. Nauk, 1995, p. 16.

    Google Scholar 

  7. Bagirzade, G.A., Abstracts of Papers, II Mezhdunar. konf. RHO im. D.I. Mendeleeva “Khimicheskaya tekhnologiya i biotekhnologiya novykh materialov i produktov” (IV Int. Conf. of the Mendeleev Russian Chemical Society “Chemical Technology and Biotechnology of New Materials and Products”), Moscow: RHTU im. D.I. Mendeleeva, 2010, p. 197.

    Google Scholar 

  8. Bagirzade, G.A. and Tagiev, D.B., Abstracts of Papers, IV Mezhdunar. konf. RHO im. D.I. Mendeleeva “Khimicheskaya tekhnologiya i biotekhnologiya novykh materialov i produktov” (IV Int. Conf. of the Mende-leev Russian Chemical Society “Chemical Technology and Biotechnology of New Materials and Products”), Moscow: RHTU im. D.I. Mendeleeva, 2012, vol. 1, p. 9.

    Google Scholar 

  9. Mikhalenko, S.A., Derkacheva, V.M., and Luk’yanets, E.A., Zh. Obshch. Khim., 1981, vol. 51, no. 7, p. 1650.

    CAS  Google Scholar 

  10. Sokolovskii, V.D., Partsial’noe okislenie organicheskikh soedinenii (Partial Oxidation of Organic Compounds), Moscow: Nauka, 1985, vol. 19, p. 99.

    Google Scholar 

  11. Bagirzade, G.A., Azerb. Khim. Zh., 2010, no. 1, p. 166.

    Google Scholar 

  12. Shapovalov, A.A., Sembaev D.H., and Suvorov, B.V., USSR Inventor’s Certificate no. 1057491, 1982, Byull. Izobret., 1983, no. 44.

    Google Scholar 

  13. Bagirzade, G.A., Azerb. Khim. Zh., 2009, no. 4, p. 163.

    Google Scholar 

  14. Saito S. and Ota, N., J. Soc. Org. Synth. Chem. Jpn., 1964, vol. 22, no. 9, p. 730.

    Article  CAS  Google Scholar 

  15. Bagirzade, G.A., Sheinin, V.E., and Magerramova, Z.Yu., Abstracts of Papers, I Mezhdunar. konf. RHO im. D.I. Mendeleeva “Resurso- i energosberegayushchie tekhnologii v khimicheskoi i neftekhimicheskoi promyshlennosti” (I Int. Conf. of the Mendeleev Russian Chemical Society “Resource- and Energy-Saving Technologies in Chemical and Petrochemical Industries”), Moscow: RHTU im. D.I. Mendeleeva, 2009, p. 94.

    Google Scholar 

  16. Bagirzade, G.A., Sheinin, V.E., Magerramova, Z.Yu., and Rizaev, R.G., Azerb. Khim. Zh., 2000, no. 1, p. 60.

    Google Scholar 

  17. Bagirzade, G.A., Abstracts of Papers, III Mezhdunar. konf. RHO im. D.I. Mendeleeva “Resurso- i energosberegayushchie tekhnologii v khimicheskoi i neftekhimicheskoi promyshlennosti” (III Int. Conf. of the Mendeleev Russian Chemical Society “Resource- and Energy-Saving Technologies in Chemical and Petrochemical Industries”), Moscow: RHTU im. D.I. Mendeleeva, 2011, p. 133.

    Google Scholar 

  18. Magerramova, Z.Yu., Doctoral (Chem.) Dissertation, Baku, 1993.

    Google Scholar 

  19. Rizaev, R.G., Bagirzade, G.A., Sheinin, V.E., Magerramova, Z.Yu., Guseinov, I.A., and Akhmedov, M.M., Abstracts of Papers, Nauch. konf. posvyaschennaya 95-letnemu yubileyu akad. M.F. Nagiev (Scientific Conf. Dedicated to the 95th Anniversary of Birth of Acad. M.F. Nagiev), Baku: IHP NANA, 2003, p. 14.

    Google Scholar 

  20. Nagiev, M.F., Teoriya retsirkulyatsii i povyshenie optimal’nosti khimicheskih protsessov (Theory of Recirculation and Optimization of Chemical Processes), Moscow: Nauka, 1970.

    Google Scholar 

  21. Rizaev, R.G., Sheinin, V.E., Bagirzade, G.A., Magerramova, Z.Yu., and Alieva, T.Ch., USSR Inventor’s Certificate no. 1728240, 1989, Byull. Izobret., 1992, no. 15.

    Google Scholar 

  22. Golodets, G.I., Partsial’noe okislenie organicheskikh soedinenii (Partial Oxidation of Organic Compounds), Moscow: Nauka, 1985, vol. 19, p. 28.

    Google Scholar 

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Authors and Affiliations

  1. Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, pr. G. Dzhavida 29, Baku, Az1143, Azerbaijan

    G. A. Bagirzade

  2. Azerbaijan Medical University, Baku, Azerbaijan

    D. B. Tagiev

Authors
  1. G. A. Bagirzade
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  2. D. B. Tagiev
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Correspondence to G. A. Bagirzade.

Additional information

Original Russian Text © G.A. Bagirzade, D.B. Tagiev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 902–907.

For communication IV, see [1].

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Bagirzade, G.A., Tagiev, D.B. Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: V. Synthesis of 4-bromophthalonitrile. Russ J Gen Chem 84, 1085–1090 (2014). https://doi.org/10.1134/S107036321406005X

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  • DOI: https://doi.org/10.1134/S107036321406005X

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