Skip to main content
Log in

Thermodynamic parameters of sublimation of acrylic acid phenyl- and furyl-containing derivatives

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Temperature dependence of saturated vapor pressure has been determined for five phenyl and furyl derivatives of acrylic acid. Processing of the experimental data has given standard enthalpy, entropy, and the Gibbs free energy of sublimation of the studied compounds. Additivity of the sublimation enthalpies has been confirmed, and enthalpies of sublimation of the constituting fragments have been calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Plate, N.A. and Slivinskii E.V., Osnovy khimii i tekhnologii monomerov (Fundamentals of Chemistry and Technology of Monomers), Moscow: Nauka, 2002.

    Google Scholar 

  2. Gavrilin, M.V., Pharm. Chem. J., 2001, no. 1, p. 35.

    Google Scholar 

  3. RF Patent 2039044, 1995.

  4. Lebedev, Yu.A. and Miroshnichenko, E.A., Termokhimiya paroobrazovaniya organicheskikh veshchestv (Thermochemistry of Vaporization of Organic Substances), Moscow: Nauka, 1981.

    Google Scholar 

  5. Nesmeyanov, A.N., Davlenie para khimicheskikh elementov (Vapor Pressure of the Chemical Elements), Moscow: Akad. Nauk SSSR, 1961.

    Google Scholar 

  6. Dibrivnyi, V.N., Butylina, N.A., Kochubei, V.V., and Van-Chin-Syan, Yu.Ya., Ukr. Khim. Zh., 1992, vol. 72, no. 8, p. 94.

    Google Scholar 

  7. Chickoks, J.S. and Acree, W.E., J. Phys. Chem. Ref. Data, 2003, vol. 32, no. 2, p. 519. DOI: 10.1063/1.529214.

    Article  Google Scholar 

  8. Chickoks, J.S., Hosseini, S., Hesse, D.G., and Liebman, J.F., Struct. Chem., 1993, no. 4, p. 271. DOI:10.1007/BF00673701.

    Google Scholar 

  9. Sabbah, R., An Xu-wu, J.S., and Planas Leitao, M.V., Thermochim. Acta, 1999, vol. 331, p. 93. DOI: 10.1016/S0040-6031(99)00009-X.

    Article  CAS  Google Scholar 

  10. Obushak, N.D., Ganushchak, N.I., Daikovskaya, L.M., and Kimlitsa, P.P., Zh. Org. Khim., 1990, vol. 26, no. 4, p. 873.

    CAS  Google Scholar 

  11. Freunal, W., J. Chem. Soc., 1963, no. 3, p. 3068. DOI: 10.1039/JR9520003068.

    Google Scholar 

  12. Ganushchak, N.I., Lesyuk, A.I., and Obushak, N.D., Zh. Org. Khim., 1992, vol. 28, no. 3, p. 531.

    CAS  Google Scholar 

  13. Ribeiro da Silva, A.V.M. and Monte, J.S.M., Thermochim. Acta, 1990, vol. 171, p. 169. DOI: 10.1016/0040-6031(90)87017-7.

    Article  CAS  Google Scholar 

  14. Krasulin, A.P., Kozyro, A.A., and Kabo, G.Ya., Zh. Prikl. Khim., 1987, vol. 60, no. 1, p. 104.

    CAS  Google Scholar 

  15. Dibrivnyi, V.M., Doctoral (Chem.) Dissertation, Lviv, 2008.

  16. Pound, G.M., J. Phys. Chem. Ref. Data, 1972, vol. 1, p. 135.

    Article  CAS  Google Scholar 

  17. Somorjain, G.A., Sci., 1968, vol. 162, p. 755. DOI: 10.1126/science.162.3855.755.

    Article  Google Scholar 

  18. De Kruif, G.G., Thermochemistry and Its Application to Chemical, Biochemical System. Proc. NATO Adv. Study Inst. Thermochem., Today: D Reidel, 1984, p. 143.

    Book  Google Scholar 

  19. Kennard, E.H., Kinetic Theory of Gases with an Introduction to Statistical Mechanics, New York, 1938.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. N. Dibrivnyi.

Additional information

Original Russian Text © V.N. Dibrivnyi, Yu.A. Raevskii, V.V. Sergeev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 885–889.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dibrivnyi, V.N., Raevskii, Y.A. & Sergeev, V.V. Thermodynamic parameters of sublimation of acrylic acid phenyl- and furyl-containing derivatives. Russ J Gen Chem 84, 1069–1073 (2014). https://doi.org/10.1134/S1070363214060024

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214060024

Keywords

Navigation