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Formation of (C x H2x+1)4NBr·nH2O (x = 1–3) hydrate

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Abstract

The phase diagram of the binary system tetramethylammonium bromide-water was studied by the differential thermal analysis. In the stable region two phases, ice and the salt itself, were detected, and in the metastable region, three tetramethylammonium bromide hydrates (bromide-water, 1 : 4, mp 68.8°C, 1 : 5, mp 36.0°C, 1 : 7.5, mp −19.5°C) were found. Formation of (C x H2x+1)4NBr·nH2O (x = 1–3, n = 4, 5, 7.5) hydrates was revealed.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 3, Novosibirsk, 630090, Russia

    L. S. Aladko

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  1. L. S. Aladko
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Correspondence to L. S. Aladko.

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Original Russian Text © L.S. Aladko, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 881–884.

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Aladko, L.S. Formation of (C x H2x+1)4NBr·nH2O (x = 1–3) hydrate. Russ J Gen Chem 84, 1065–1068 (2014). https://doi.org/10.1134/S1070363214060012

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  • DOI: https://doi.org/10.1134/S1070363214060012

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