Abstract
Interaction between hydroxyoxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V) and 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin-2-yl)methylpyrrolidinyl[60]fullerene in toluene has been studied by means of spectrophotometry. The reaction proceeds via two stages: rapidly established equilibrium between the reactants and their molecular complex 1: 1 [K = (1.97 ± 0.52) × 104 L/mol] followed by slow irreversible displacement of hydroxy group into the second coordination sphere to form cationic outer sphere complex (k = 0.26 L s−1 mol−1). The effect of fullerene fragment on pyridine fragments coordination has been considered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Konarev, D.V. and Lyubovskaya, R.N., Russ. Chem. Bull., 1999, vol. 68, no. 3, p. 19.
Pal, D., Ray, A., and Bhattacharya, S., Spectrochim. Acta (A), 2012, vol. 95, no. 9, p. 317.
Mironov, A.F., Macroheterocycles, 2011, vol. 4, no. 3, p. 186.
Rather, J.A. and De Wael, K., Sensors and Actuators (B), 2013, vol. 176, p. 110.
Sandanayaka, A.S.D., Murakami, T., and Hasobe, T., J. Phys. Chem. (C), 2009, vol. 113, no. 42, p. 18369.
Walter, M.G., Rudine, A.B., and Wamser, C.C., J. Porphyrins and Phthalocyanines, 2010, vol. 14, no. 9, p. 759.
Li, M., Ishihara, Sh., Ji, Q., Akada, M., Hill, J.P., and Ariga, K., Sci. Technol. Adv. Mater., 2012, vol. 13, p. 1.
Troshin, P.A. and Lyubovskaya, R.N., Russ. Chem. Rev., 2008, vol. 77, no. 4, p. 323.
Troshin, P.A., Troyanov, S.I., Boiko, G.N., Lyubovskaya, R.N., Lapshin, A.N., and Goldshleger, N.F., Fullerenes Nanotubes and Carbon Nanostructures, 2004, vol. 12, nos. 1–2, p. 435.
Nanostrukturirovannye materialy dlya zapasaniya i preobrazovaniya energii (Nanostructured Materials for Energy Conversion and Storing), Razumov, V.F. and Klyuev, M.V., Eds., Ivanovo: Ivanov. Gos. Univ., 2009.
Lomova, T.N., Malov, M.E., and Klyuev, M.V., Russ. J. Phys. Chem. A., 2009, vol. 83, no. 6, p. 913.
Tipugina, M.Yu., Lomova, T.N., and Motorina, E.V., Russ. J. Coord. Chem., 2005, vol. 31, no. 5, p. 357.
Lomova, T.N. and Malov, M.E., Tezisy dokl. X Mezhdunar. konf. po fiz. i koord. khimii porfirinov i ikh analogov (X Int. Conf. of Physical and Coordination Chemistry of Porphyrins and Their Analogues), Ivanovo, 2009, p. 42.
Motorina, E.V. and Lomova, T.N., Tezisy dokl. VII Mezhdunar. nauch. konf. “Kinetika i mekhanizm kristallizatsii. Kristallizatsiya i materialy novogo pokoleniya” (VII Int. Sci. Conf. “Kinetics and Mechanism of Crystallization. Crystallization and Materials of New Generation”), Ivanovo, 2012, p. 159.
Gasanov, R.G., Lobach, A.S., Sokolov, V.I., Demenjev, A.P., Maslakov, K.I., and Obraztsova, E.D., J. Nanosci. Nanotechnol., 2007, vol. 7, p. 1546.
Bashilov, V.V., Tumanskii, B.L., Petrovskii, P.V., and Sokolov, V.I., Russ. Chem. Bull., 1994, vol. 43, no. 6, p. 1069.
Sokolov, V.I., Gasanov, R.G., Goh, L.Y., Weng, Z., Chistyakov, A.L., and Stankevich, I.V., J. Organomet. Chem., 2005, vol. 690, no. 9, p. 2370.
Islamova, N.I., Candidate Sci. (Chem.) Dissertation, Ivanovo, 2005.
Lapshin, A.N., Candidate Sci. (Chem.) Dissertation, Ivanovo, 2006.
Lomova, T.N., Volkova, N.I., and Berezin, B.D., Zh. Neorg. Khim., 1985, vol. 30, no. 3, p. 626.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Motorina, T.N. Lomova, P.A. Troshin, M.V. Klyuev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 855–861.
Rights and permissions
About this article
Cite this article
Motorina, E.V., Lomova, T.N., Troshin, P.A. et al. Novel 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin-2-yl)methylpyrrolidinyl[60]fullerene-hydroxyoxo(5,10,15,20-tetraphenyl-21H,23H-porphynato) molybdenum(V) dyads. Russ J Gen Chem 84, 946–952 (2014). https://doi.org/10.1134/S1070363214050272
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363214050272