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Influence of substituents structure and their electronic effects on acid-base and complexing properties of 5,10,15,20-tetranitro-2,3,7,8,12,13,17,18-octaethylporphyrin

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Abstract

5,10,15,20-Tetranitro-2,3,7,8,12,13,17,18-octaethylporphyrin has been prepared, and its acid-basic properties have been studied in acetonitrile by titration with 1,8-diazabicyclo [5.4.0]undec-7-ene and perchloric acid. The substituted porphyrin ability towards complex formation with zinc acetate has been studied in acetonitrile and acetonitrile, 1,8-diazabicyclo [5.4.0]undec-7-ene media. Spectral properties of neutral and ionic forms of 5,10,15,20-tetranitro-2,3,7,8,12,13,17,18-octaethylporphyrin and its zinc complex have been determined; constants of acid and basic ionization of the ligand have been estimated. Kinetic parameters of the porphyrin complex formation with zinc via molecular and ionic mechanism have been analyzed. The substituents effect on the studied properties is discussed.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. B. Ivanova, N. V. Chizhova & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    S. G. Pukhovskaya

Authors
  1. Yu. B. Ivanova
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  2. N. V. Chizhova
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  3. S. G. Pukhovskaya
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  4. N. Zh. Mamardashvili
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Correspondence to Yu. B. Ivanova.

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Original Russian Text © Yu.B. Ivanova, N.V. Chizhova, S.G. Pukhovskaya, N.Zh. Mamardashvili, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 848–854.

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Ivanova, Y.B., Chizhova, N.V., Pukhovskaya, S.G. et al. Influence of substituents structure and their electronic effects on acid-base and complexing properties of 5,10,15,20-tetranitro-2,3,7,8,12,13,17,18-octaethylporphyrin. Russ J Gen Chem 84, 939–945 (2014). https://doi.org/10.1134/S1070363214050260

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  • DOI: https://doi.org/10.1134/S1070363214050260

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