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Dimephosphone analogs: II. Dialkyl(diaryl)-(2-methyl-4-oxopent-2-yl)phosphine oxide oximes: Synthesis, structure, and generation of iminoxyl radicals

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Abstract

Dialkyl(diaryl)-(2-methyl-4-oxopent-2-yl)phosphine oxide oximes have been synthesized for the first time. According to the X-ray diffraction data, these compounds in crystal exist as a single E isomer. Their structure in solution and the E/Z isomer ratio were determined by 1H and 13C NMR spectroscopy.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    D. A. Tatarinov, V. F. Mironov, A. A. Kostin, E. V. Mironova, D. B. Krivolapov, V. I. Morozov, V. N. Nabiullin, A. V. Il’yasov & B. I. Buzykin

Authors
  1. D. A. Tatarinov
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  2. V. F. Mironov
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  3. A. A. Kostin
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  4. E. V. Mironova
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  5. D. B. Krivolapov
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  6. V. I. Morozov
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  7. V. N. Nabiullin
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  8. A. V. Il’yasov
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  9. B. I. Buzykin
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Correspondence to D. A. Tatarinov.

Additional information

Original Russian Text © D.A. Tatarinov, V.F. Mironov, A.A. Kostin, E.V. Mironova, D.B. Krivolapov, V.I. Morozov, V.N. Nabiullin, A.V. Il’yasov, B.I. Buzykin, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 808–817.

For communication I, see [1].

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Tatarinov, D.A., Mironov, V.F., Kostin, A.A. et al. Dimephosphone analogs: II. Dialkyl(diaryl)-(2-methyl-4-oxopent-2-yl)phosphine oxide oximes: Synthesis, structure, and generation of iminoxyl radicals. Russ J Gen Chem 84, 901–910 (2014). https://doi.org/10.1134/S107036321405020X

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