Skip to main content
Log in

Pyrocatechol and its derivatives as antioxidants and prooxidants

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The effect of pyrocatechol and its derivatives (4,5-dichloro- and 4,5-dibromo pyrocatechols, veratrol, 4,5-dichloro- and 4,5-dibromoveratrol) on the free-radical oxidation of propan-2-ol in aqueous solutions, initiated by γ-radiation. Pyrocatechol and dihalocatechols exhibit antioxidant properties, whereas dihaloveratrols exhibit prooxidant properties. Dibromoveratrol showed more expressed prooxidant properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Halliwell, B. and Gutteridge, J.M.C., Free Radicals in Biology and Medicine, Oxford: Oxford Univ. Press, 1999.

    Google Scholar 

  2. Shugalei, I.V. and Tselinskii, I.V., Russ. J. Gen. Chem., 2000, vol. 70, no. 7, p. 991.

    CAS  Google Scholar 

  3. Henly, E. and Johnson, E., The Chemistry and Physics of High Energy Reactions, Washington, DC: University Press, 1969.

    Google Scholar 

  4. Pikaev, A.K., Sovremennaya radiatsionnaya khimiya. Radioliz gazov i zhidkostei (Modern Radiation Chemistry. Radiolysis of Gases and Liquids), Moscow: Nauka, 1986.

    Google Scholar 

  5. Buxton, G.V., Greenstock, C.L., Helman, W.P., and Ross, A.B., J. Phys. Chem. Ref. Data, 1988. vol. 17, no. 2, p. 513.

    Article  CAS  Google Scholar 

  6. Bugaenko, V.L. and Byakov, V.M., Khim. Vys. Energ., 1998, vol. 32, no. 6, p. 407.

    Google Scholar 

  7. von Sonntag, C., The Chemical Basis of Radiation Biology, London: Taylor & Francis, 1987.

    Google Scholar 

  8. Ilan, Y., Rabani, J., and Henglein, A., J. Phys. Chem., 1976, vol. 80, no. 14, p. 1558.

    Article  CAS  Google Scholar 

  9. Schuchman, M.N. and von Sonntag, C., J. Phys. Chem., 1982, vol. 86, no. 11, p. 1995.

    Article  Google Scholar 

  10. Weinstein, J. and Bielski, B.H.J., J. Am. Chem. Soc., 1979, vol. 101, no. 1, p. 58.

    Article  CAS  Google Scholar 

  11. Maiboroda, V.D., Petryaev, E.P., Byakov, V.M., and Ivashkevich, L.F., Khim. Vys. Energ., 1974, vol. 8, no. 3, p. 284.

    CAS  Google Scholar 

  12. Rao, P.S. and Hayon, E., J. Phys. Chem., 1975, vol. 79, no. 2, p. 397.

    Article  CAS  Google Scholar 

  13. Schuler, R.H., Neta, P., Zemel, H., and Fessenden, R.W., J. Am. Chem. Soc., 1976, vol. 98, no. 13, p. 3825.

    Article  CAS  Google Scholar 

  14. Kosobutskii, V.S., Russ. J. Gen. Chem., 2009, vol. 79, no. 3, p. 408.

    Article  CAS  Google Scholar 

  15. Anbar, M. and Hart, E.J., J. Am. Chem. Soc., 1964, vol. 86, no. 7, p. 5633.

    Article  CAS  Google Scholar 

  16. Tietze, L.F. and Eicher, T., Reaktionen und Synthesen im organisch-chemischen Praktikum und Forschungslaboratorium, Stuttgart: Thieme, 1991.

    Book  Google Scholar 

  17. Kajigaeshi, S., Shinmasu, Y., Fujisaki, S., and Kakinami, T., Chem. Lett., 1989, no. 3, p. 415.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. S. Kosobutskii.

Additional information

Original Russian Text © V.S. Kosobutskii, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 746–749.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kosobutskii, V.S. Pyrocatechol and its derivatives as antioxidants and prooxidants. Russ J Gen Chem 84, 839–842 (2014). https://doi.org/10.1134/S1070363214050090

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214050090

Keywords

Navigation