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Radiochemical study of gas-phase reactions of diethylstannyl cations Et2SnT+ with oxygen-containing compounds: II. Reaction of diethylstannyl cations with butanol

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Abstract

Gas-phase reaction of nucleogenic diethylstannyl cations Et2SnT+ with butan-1-ol has been studied by the radiochemcal method, and probable reaction mechanisms have been proposed. During the process diethylstannyl cations undergo isomerization into tertiary Me2EtSn+ cations and rearrangement with elimination of ethane. Thermochemical parameters of reactions of diethyl-substituted cations derived from Group 14 elements (Et2TM+; M = C, Si, Ge, Sn) with alcohols have been analyzed by the M06L aug-cc-pVDZ quantum chemical method.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. A. Alferova, V. V. Avrorin, E. N. Sinotova & I. S. Ignat’ev

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    T. A. Kochina

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  1. A. A. Alferova
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  2. T. A. Kochina
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  3. V. V. Avrorin
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  4. E. N. Sinotova
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  5. I. S. Ignat’ev
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Correspondence to T. A. Kochina.

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Original Russian Text © A.A. Alferova, T.A. Kochina, V.V. Avrorin, E.N. Sinotova, I.S. Ignat’ev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 723–728.

For communication I, see [1].

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Alferova, A.A., Kochina, T.A., Avrorin, V.V. et al. Radiochemical study of gas-phase reactions of diethylstannyl cations Et2SnT+ with oxygen-containing compounds: II. Reaction of diethylstannyl cations with butanol. Russ J Gen Chem 84, 816–821 (2014). https://doi.org/10.1134/S1070363214050041

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  • DOI: https://doi.org/10.1134/S1070363214050041

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