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Study of photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol

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Abstract

Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

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Authors and Affiliations

  1. Tomsk Polytechnic University, pr. Lenina 30, Tomsk, 634050, Russia

    N. B. Egorov, K. B. Obmuch & V. F. Usov

  2. Yurga Technology Institute, Tomsk Polytechnic University Branch, Tomsk, Russia

    L. P. Eremin

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  1. N. B. Egorov
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  2. L. P. Eremin
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  3. K. B. Obmuch
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  4. V. F. Usov
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Correspondence to N. B. Egorov.

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Original Russian Text © N.B. Egorov, L.P. Eremin, K.B. Obmuch, V.F. Usov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 705–710.

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Egorov, N.B., Eremin, L.P., Obmuch, K.B. et al. Study of photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol. Russ J Gen Chem 84, 799–803 (2014). https://doi.org/10.1134/S1070363214050016

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  • DOI: https://doi.org/10.1134/S1070363214050016

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