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Phenylenediamine and 4,4′-diaminodiphenyls in cyclothiomethylation with CH2O and H2S

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Abstract

Cyclothiomethylation of o-phenylenediamine with CH2O and H2S gives rise to 1,2,4,5-tetrahydrobenzo[d][1,3,6]thiadiazepine and 1,2,6,7-tetrahydrobenzo[f][1,3,5,8]dithiadiazonine, whereas m-phenylenediamine forms benzothiaza macroheterocycles of various structure, comprising 4–8 molecules of the starting diamine, formaldehyde, and hydrogen sulfide. 4,4′-Diaminodiphenyls give bis(1,3,5-dithiazinanes), along with oligomeric hetero(N,S,O)atomic compounds.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Avademy of Sciences, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075, Russia

    G. R. Khabibullina & V. R. Akhmetova

  2. Ufa State Academy of Economy and Service, Ufa, Bashkortostan, Russia

    R. V. Kunakova

Authors
  1. G. R. Khabibullina
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  2. V. R. Akhmetova
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  3. R. V. Kunakova
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Correspondence to G. R. Khabibullina.

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Original Russian Text © G.R. Khabibullina, V.R. Akhmetova, R.V. Kunakova, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 4, pp. 614–620.

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Khabibullina, G.R., Akhmetova, V.R. & Kunakova, R.V. Phenylenediamine and 4,4′-diaminodiphenyls in cyclothiomethylation with CH2O and H2S. Russ J Gen Chem 84, 693–699 (2014). https://doi.org/10.1134/S107036321404015X

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  • DOI: https://doi.org/10.1134/S107036321404015X

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