Russian Journal of General Chemistry

, Volume 84, Issue 3, pp 555–561 | Cite as

Local surrounding of cobalt(II) in dithiocarbamate complexes, their magnetic and spectral properties

  • N. V. Khitrich
  • V. G. Vlasenko
  • I. I. Seifullina
  • Ya. V. Zubavichus
  • S. I. Levchenkov
  • L. S. Skorokhod


[Co(S2CNRR’)2] complexes [R = R’ = CH3, C2H5, C3H7, C4H9, or CH2C6H5; RR’ = (CH2)5, (CH2)6, or (CH2)2O(CH2)2] were prepared via interaction of CoCl2 with sodium dithiocarbamates in aqueous medium (pH 6–7). [Co(S2CNRR’)2] are low-spin compounds (μeff 2.19–2.45 μB) with distorted square-planar geometry of the CoS4 coordination node. The Co-S bonds length is 2.22–2.26 Å, and the distance between cobalt and carbon atoms is 2.73–2.74 Å.


Cobalt General Chemistry Dithiocarbamate XANES Spectrum EXAFS Spectrum 
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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • N. V. Khitrich
    • 1
  • V. G. Vlasenko
    • 2
  • I. I. Seifullina
    • 1
  • Ya. V. Zubavichus
    • 3
  • S. I. Levchenkov
    • 4
  • L. S. Skorokhod
    • 1
  1. 1.Mechnikov Odessa State National UniversityOdessaUkraine
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.National Research Center “Kurchatov Institute,”MoscowRussia
  4. 4.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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