Abstract
Reaction of tetrachlorogermane with 2-thienylchlorosilane and methyl(2-thienyl)dichlorosilane in presence of AlCl3 is studied. It was shown that in the reaction with 2-thienyltrichlorosilane 2-thienyltrichlorogermane mainly formed, while in the reactions with methyl(2-thienyl)dichlorosiulane aromatic germaniumcontaining compounds like 2-thienyltrichlorogermane and di(2-thienyl)dichlorogermane were obtained. Quantum-chemical calculations showed that the reaction of chlorine atoms exchange in GeCl4 with aromatic moiety formed from arylchlorosilanes in the presence of AlCl3 proceeds through a four-membered activated complex.
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Original Russian Text © V.G. Lakhtin, M.I. Vorob’eva, E.G. Gordeev, V.N. Ushakov, A.D. Kirillin, V.G. Bykovchenko, N.A. Golub, E.A. Chernyshev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 2, pp. 288–292.
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Lakhtin, V.G., Vorob’eva, M.I., Gordeev, E.G. et al. Reaction of tetrachlorogermane with thienyl- and phenylchlorosilanes in presence of aluminum chloride. Synthesis of thienylchlorogermanes. Russ J Gen Chem 84, 280–284 (2014). https://doi.org/10.1134/S1070363214020212
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DOI: https://doi.org/10.1134/S1070363214020212