Skip to main content
SpringerLink
Log in

Effect of metal cation surrounding on the redox properties of aluminum porphyrinate in the reaction with organic peroxide

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Intermolecular interaction of aluminum(III) 5,15-di(o-methoxyphenyl)-2,8,12,18-tetrabutyl-3,7,13.17-tetramethylporphyrinate chloride with bis(1-methyl-1-phenylethyl)peroxide has been studied by spectral and modeling methods; the reaction kinetics and mechanism have been elucidated. Effect of nature of the metal outer coordination sphere on the reaction rate has been examined. Geometry parameters of the initial molecules and the intermediates have been simulaed by the PM3 method, and their distortion has been estimated. The intermediates formation is accompanied by increased steric strain of the macrocycle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Konovalova, N.V., Evstigneeva, R.P., and Luzgina, V.N., Russ. Chem. Rev., 2001, vol. 70, no. 11, p. 939.

    Article  CAS  Google Scholar 

  2. Mamardashvili, G.M., Mamardashvili, N.Zh., and Koifman, O.I., Russ. Chem. Rev., 2005, vol. 74, no. 8, p. 765.

    Article  CAS  Google Scholar 

  3. Mamardashvili, G.M., Mamardashvili, N.Zh., and Koifman, O.I., Russ. Chem. Rev., 2008, vol. 77, no. 1, p. 59.

    Article  CAS  Google Scholar 

  4. Koifman, O.I. and Mamardashvilim, N.Zh., Nanotechnol. in Russia, 2009, vol. 4, nos. 5–6, p. 253.

    Article  Google Scholar 

  5. Afanasiev, P., Bouchu, D., Kudrik, E.V., Millet, J.-M.M., and Sorokin, A.B., Dalton Trans., 2009, vol. 38, no. 44, p. 9828.

    Article  Google Scholar 

  6. Kudrik, E.V., Afanasiev, P., Alvarez, L.X., and Dudourdeaux, P., Nature Chem., 2012, vol. 4, no. 12, p. 1024.

    Article  CAS  Google Scholar 

  7. Zaitseva, S.V., Zdanovich, S.A., and Koifman, O.I., Russ. J. Gen. Chem., 2006, vol. 76, no. 10, p. 1660.

    Article  CAS  Google Scholar 

  8. Sokolova, T.N., Lomova, T.N., Zaitseva, S.V., Zdanovich, S.A., Suslova, E.E., and Maizlish, V.E., Russ. J. Inorg. Chem., 2005, vol. 50, no. 3, p. 476.

    Google Scholar 

  9. Zaitseva, S.V., Zdanovich, S.A., and Koifman, O.I., Russ. J. Coord. Chem., 2010, vol. 36, no. 5, p. 323.

    Article  CAS  Google Scholar 

  10. Sokolova, T.N., Lomova, T.N., Zaitseva, S.V., Zdanovich S.A., and Majzlish V.E., Russ. J. Inorg. Chem., 2008, vol. 53, no. 2, p. 220.

    Google Scholar 

  11. Bulatov, M.I. and Kalinkin, I.P., Prakticheskoe rukovodstvo po fotokolometricheskim i spektrofotometricheskim metodam analiza (Practical Guide to Photocolorimetry and Spectrophotometric Methods of Analysis), Leningrad: Khimiya, 1968.

    Google Scholar 

  12. Stewart, J.J.P., J. Comput. Chem., 1989, vol. 10, no. 2, p. 221.

    Article  CAS  Google Scholar 

  13. Stewart, J.J.P., J. Comp.-Aided Mol. Des., 1990, vol. 4, p. 1.

    Article  Google Scholar 

  14. Fletcher, R., Methods of Optimization, New York: John Wiley & Sons, 1980, p. 45.

    Google Scholar 

  15. Liston, D.J. and West, B.O., Inorg. Chem., 1985, vol. 24, no. 10, p. 1568.

    Article  CAS  Google Scholar 

  16. Kalish, H., Camp, J.E., Stepien, M., Latos-Grazynski, L., and Balch, A.L., J. Am. Chem. Soc., 2001, vol. 123, no. 47, p. 11719.

    Article  CAS  Google Scholar 

  17. Berezin, B.D. and Sennikova, G.V., Kinetika i Kataliz, 1968, vol. 9, no. 3, p. 528.

    CAS  Google Scholar 

  18. Simonova, O.R., Zaitseva, S.V., and Koifman, O.I., Russ. J. Coord. Chem., 2009, vol. 35, no. 5, p. 320.

    Article  CAS  Google Scholar 

  19. Bagdasaryan, Kh.S., Teoriya radikal’noi polimerizatsii (Theory of Radical Polymerization), Moscow: Nauka, 1966, p. 300.

    Google Scholar 

  20. Cheremenskaya, O.V., Solov’eva, F.B., and Ponomarev, G.V., Russ. J. Phys. Chem., A, 2001, vol. 75, no. 10, p. 1633.

    Google Scholar 

  21. Lindsey, J.S. and Woodford, J.N., Inorg. Chem., 1995, no. 34, p. 1063.

    Google Scholar 

  22. Semeikin, A.S., Koifman, O.I., and Berezin, B.D., Chem. Heterocyc. Comp., 1982, no. 10, p. 1046.

    Google Scholar 

  23. Eksperimental’nye metody khimicheskoi kinetiki (Experimental Methods of Chemical kinetics), Emanuel’, N.M. and Sergeev, G.B., Eds., Moscow: Vysshaya Shkola, 1980.

    Google Scholar 

  24. Bersuker I.B., Electronic Structure and Properties of Transition Metal Compounds, New York: Willey, 1996.

    Google Scholar 

  25. Schidt, M.W., Baldridge, K.K., Boatz, J.A., Elbert, S.T., Gordon, M.S., Jensen, J.H., Koseki, S., Matsunaga, N., Nguyen, K.A., Su, S., Windus, T.L., Dupuis, M., and Montgomeri, J.A., J. Comput. Chem., 1993, vol. 14, no. 11, p. 1347.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. R. Simonova, S. V. Zaitsev & O. I. Koifman

  2. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    O. I. Koifman

Authors
  1. O. R. Simonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Zaitsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. I. Koifman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Zaitsev.

Additional information

Original Russian Text © O.R. Simonova, S.V. Zaitsev, O.I. Koifman, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 114–120.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Simonova, O.R., Zaitsev, S.V. & Koifman, O.I. Effect of metal cation surrounding on the redox properties of aluminum porphyrinate in the reaction with organic peroxide. Russ J Gen Chem 84, 108–114 (2014). https://doi.org/10.1134/S1070363214010174

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214010174

Keywords

Search

Navigation