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Reaction of P(III) chlorides with aldehydes: III. Reaction of primary intermediates with oxidants and chlorinating agents

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Abstract

Primary intermediates of P(III) chlorides reaction with aldehydes have been converted into the corresponding phosphates by treating with oxidants: dimethylsulfoxide and tert-butyl hypochlorite. In reactions of the intermediates with chlorinating agents (PCl5 and Cl2) the oxidation products are formed (due to the ligand exchange at quasiphosphonium center) along with the expected P(IV) acid chlorides.

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Authors and Affiliations

  1. Kazan National Research Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia

    M. B. Gazizov, R. A. Khairullin & R. F. Karimova

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  1. M. B. Gazizov
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  2. R. A. Khairullin
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  3. R. F. Karimova
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Correspondence to M. B. Gazizov.

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Original Russian Text © M.B. Gazizov, R.A. Khairullin, R.F. Karimova, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 79–85.

For communication II, see [1].

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Gazizov, M.B., Khairullin, R.A. & Karimova, R.F. Reaction of P(III) chlorides with aldehydes: III. Reaction of primary intermediates with oxidants and chlorinating agents. Russ J Gen Chem 84, 75–81 (2014). https://doi.org/10.1134/S1070363214010113

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  • DOI: https://doi.org/10.1134/S1070363214010113

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