Abstract
Platinum and palladium nanoparticles of 4–5 nm size applied at nanodiamonds have been shown to efficiently catalyze liquid-phase hydrogenation of different organic compounds (nitrocompounds, azomethines, and unsaturated hydrocarbons and alcohols) under mild conditions (T = 318 K, hydrogen pressure of 0.1 MPa, solution in ethanol). Using of palladium on nanodiamond containing 3 wt % of metal has been most efficient.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Klyuev, M.V., Volkova, T.G., and Magdalinova, N.A., Organicheskie i gibridnye materially (Organic and Hybrid Materials), Razumov V.F., and Klyuev M.V., Eds., Ivanovo: Ivanov. Gos. Univ., 2009, p. 147.
Magdalinova, N.A., Klyuev, M.V., and Volkova, T.G., Abstracts of Papers, All-Russian Sci. and Pract. Conf. “Principles of Green Chemistry and Organic Synthesis,” Yaroslavl’: YuarGU, 2009, p. 21.
Magdalinova, N.A., Klyuev, M.V., Volkova, T.G., Vershinin, N.N., Bakaev, V.A., Efimov, O.I., and Korobov, I.I., Russ. Chem. Bull., 2011, no. 6, p. 1085.
Volkova, T.G., Magdalinova, N.A., and Klyuev, M.V., Izv. Vyssh. Ucheb. Zaved., Ser. Khim. Khim. Tekhnol., 2011, vol. 56, no. 7, p. 98.
Golubina, E.V., Kachevsky, S.A., Lokteva, L.S., Lunin, V.V., Canton, P., and Tundo, P., Mendeleev Commun., 2009, vol. 19, no. 3, p. 133.
Golubina, E.V., Lokteva, E.S., Majouga, A.G., Lobanov, M.V., and Lunin, V.V., Diamond Relat. Mater., 2011, vol. 20, no. 7, p. 960.
Turova, O.V., Starodubtseva, E.V., Vinogradov, M.G., Sokolov, V.I., Abramova, N.V., Vul’, A.Ya., and Aleksenskiy, A.E., Catal. Commun., 2011, vol. 12, no. 7, p. 577.
Magdalinova, N.A., Klyuev, M.V., Volkova, T.G., Vershinina, N.N., Bakaev, V.A., and Efimov, O.N., Al’ternativnaya Energetika Ekologiya, 2010, no. 3, p. 54.
Magdalinova, N.A., Klyuev, M.V., Volkova, T.G., Vershinin, N.N., Bakaev, V.A., and Efimov, O.N., Al’ternativnaya Energetika Ekologiya, 2010, no. 11, p. 113.
Vershinin, N.N., Aleinikov, N.N., Bakaev, V.A., and Efimov, O.N., Ross. Nanotekh., 2008, nos. 5–6, p. 39.
Vershinin, N.N. and Efimov, O.N., RF Patent no. 2348090, 2009.
Vershinin, N.N., Efimov, O.N., Bakaev, V.A., Korobov, I.I., Gusev, A.L., Aleksenskiy, A.A., and Vul’, A.Ya., Abstracts of Papers, 9 Biennial Int. Workshop “Fullerenes and Atomic Clusters,” St. Petersburg, 2009, p. 239.
Efimov, O.N., Vershinin, N.N., Tatsiy, V.F., Gusev, A.L., and Gol’dshleger, N.F., Al’ternativnaya Energetika Ekologiya, 2007, no. 6, p. 98.
Morar, J.F., Himpsel, F.V., Hollinger, G., Jordan, J.L., Huges, G., and McFeely, F.R., Phys. Rev., 1986, vol. 33, p. 1340.
Lascovish, J.C., Giorgi, R., and Scaglione, S., Appl. Surf. Sci., 1991, vol. 47, p. 17.
Volkova, T.G. and Klyuev, M.V., Petrol. Chem., 1998, vol. 38, no. 3, p. 178.
Volkova, T.G., and Klyuev, M.V., Neftekhimiya, 1997, vol. 38, no. 4, p. 321.
Zhivotyagina, S.N., Candidate Sci. (Chem.) Dissertation, Ivanovo, 2005.
Usanova, N.N., Candidate Sci. (Chem.) Dissertation, Ivanovo, 2008.
Magdalinova, N.A., Candidate Sci. (Chem.) Dissertation, Ivanovo, 2009.
Granovsky, A.A., PCGAMESS version 7.1. http://classic.chem.msu.su/gran/games/index.html .
Vershinin, N.N., Bakaev, V.A., Efimov, O.N., Korobov, I.I., Gusev, A.L., Aleksenskii, A.E., Baidakova, M.V., and Vul’, A.Ya., Al’ternativnaya Energetika Ekologiya, 2009, no. 9, p. 123.
Vershinin, N.N., Bakaev, V.A., Gusev, A.L., and Efimov, O.N., Al’ternativnaya Energetika Ekologiya, 2009, no. 10, p. 85.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.A. Magdalinova, P.A. Kalmykov, M.V. Klyuev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 35–42.
Rights and permissions
About this article
Cite this article
Magdalinova, N.A., Kalmykov, P.A. & Klyuev, M.V. Hydrogenation catalysts based on platinum- and palladium-containing nanodiamonds. Russ J Gen Chem 84, 33–39 (2014). https://doi.org/10.1134/S1070363214010083
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363214010083