Skip to main content
SpringerLink
Log in

The rate of chloroacetic acid alkaline hydrolysis: Medium effect

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Rate constant of chloroacetic acid alkaline hydrolysis in the mixed aqueous-organic solvents depends on the organic co-solvent nucleophilic solvation; however, the effect of the medium polarity on the rate constant is not clear. The rate constant can be reasonably estimated with a multi-parameter equation accounting for the organic co-solvent basicity as well as its density of cohesion energy and molar volume.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ingold, K., Theoretical Foundations of Organic Chemistry, Moscow: Mиp, 1973.

    Google Scholar 

  2. Dvorko, G.F., Ponamor’ov, M.E., and Ponomar’ova, E.O., Dopov. NAN Ukrainy, 2009, no. 11, p. 141.

    Google Scholar 

  3. Abraham, M.H., Doherty, R.M., Kamlet, M.J., Harris, J.M., and Taft, R.W., J. Chem. Soc., Perkin Trans. 2, 1987, no. 7, p. 913.

    Google Scholar 

  4. Rakhmatullin, R.R. and Gavrilov, V.I., Russ. J. Gen. Chem., 2012, vol. 82, no. 2, p. 190.

    Article  CAS  Google Scholar 

  5. Makitra, R.G., Turovsky, A.A., and Zaikov, G.E., Correlation Analysis in Chemistry of Solutions, Utrecht, Boston: VST, 2004.

    Google Scholar 

  6. Recommendations for Reporting the Results of Correlation Analysis in Chemistry using Regression Analysis. Quant. Struct. Act. Relat., 1985, vol. 4, no. 1, p. 29.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physical Chemistry of Fossil Fuels InPOCC, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79053, Ukraine

    G. G. Midyana & R. G. Makitra

  2. Institute of Fossil Fuels Geology and Geochemistry, Ukraine National Academy of Sciences, Lviv, Ukraine

    E. Ya. Pal’chikova

Authors
  1. G. G. Midyana
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. G. Makitra
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Ya. Pal’chikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. G. Midyana.

Additional information

Original Russian Text © G.G. Midyana, R.G. Makitra, E.Ya. Pal’chikova, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 24–26.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Midyana, G.G., Makitra, R.G. & Pal’chikova, E.Y. The rate of chloroacetic acid alkaline hydrolysis: Medium effect. Russ J Gen Chem 84, 22–24 (2014). https://doi.org/10.1134/S107036321401006X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036321401006X

Keywords

Search

Navigation