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Preparation and properties of the MIIIU2O7.5 polyuranates (MIII = Y, Tb, Dy, Ho, Er, Tm, Yb, or Lu)

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Abstract

The novel compounds of the MIIIU2O7.5 type (with MIII being yttrium or lanthanides from terbium to lutetium) have been prepared via hydrothermal synthesis from hydrated uranium(VI) oxide and aqueous solutions of M(III) nitrates at 200°C. Composition and structure of the products have been studied by means of elemental analysis, high-temperature X-ray diffraction, and IR spectroscopy; the products thermal stability has been estimated.

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Authors and Affiliations

  1. Lobachevskii Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorog, 603095, Russia

    N. G. Chernorukov, O. V. Nipruk, M. I. Arova & K. A. Chaplieva

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  1. N. G. Chernorukov
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  2. O. V. Nipruk
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  3. M. I. Arova
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  4. K. A. Chaplieva
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Correspondence to N. G. Chernorukov.

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Original Russian Text © N.G. Chernorukov, O.V. Nipruk, M.I. Arova, K.A. Chaplieva, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 8–10.

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Chernorukov, N.G., Nipruk, O.V., Arova, M.I. et al. Preparation and properties of the MIIIU2O7.5 polyuranates (MIII = Y, Tb, Dy, Ho, Er, Tm, Yb, or Lu). Russ J Gen Chem 84, 6–8 (2014). https://doi.org/10.1134/S1070363214010022

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  • DOI: https://doi.org/10.1134/S1070363214010022

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