Abstract
Globular proteins uptake kinetics by hydrogels of oppositely charged network polyelectrolytes was studied with relation to the polyelectrolyte composition. It was shown that introduction of hydrophilic neutral units of acrylamide, inert towards proteins studied, significantly accelerated the uptake process, with no effect on the polyelectrolyte capacity towards proteins (with respect to ionic groups). The results obtained allow for optimization of the sorbent composition in order to enhance the polymeric pollutants uptake and/or tune their release rate.
Similar content being viewed by others
References
Kokufuta, E., Prog. Polym. Sci., 1992, vol. 12, p. 647.
Pelton, R., Adv. Col. Int. Sci., 2000, vol. 85, p. 1.
Kuhn, W., Hargitay, B., Katchalsky, A., and Eisenberg, H., Nature, 1950, vol. 165, p. 514
Kou, J.H., Amidon, G.L., and Lee, P.I., Pharm. Res., 1988, vol. 5, p. 592.
Kabanov, V.A., Zezin, A.B., Izumrudov, V.A., Bronich, T.K., and Bakeev, K.N., Die Makromol. Chem. Suppl., 1985, vol. 13, p. 137.
Skobeleva, V.B., Zinchenko, A.V., Rogacheva, V.B., Zezin, A.B., and Kabanov, V.A., Polymer Sci., Ser. A, 2001, vol. 43, p. 315.
Kabanov, V.A., Skobeleva, V.B., Rogacheva, V.B., and Zezin, A.B., J. Phys. Chem. B, 2004, vol. 108, p. 1485.
Crini, G., Prog. Polym. Sci., 2005, vol. 30, p. 38.
Bouranisa, D.L., Theodoropoulos, A.G., and Drossopoulos, J.B., Commun. Soil Sci. Plant Anal., 1995, vol. 26, p. 1455.
Kabanov, V.A., Vysokomol. Soedin., 1994, vol. 36, p. 183.
Skobeleva, V.B., Rudenskaya, G.N., and Rudenskaya, Yu.A., Vest. Mosk. Univ., Ser. Khim., 2000, vol. 41, p. 395.
Munjal, N. and Sawhney, S.K., Enzym. Microb. Technol., 2002, vol. 30, p. 613.
Karpushkin, E.A and Skobeleva, V.B., Coll. of Papers, Struktura i dinamika molekulyarnykh sistem (Structure and Dynamics of Molecular Systems), vyp. XI,ch. 1, Kazan, 2004, p. 274.
Durmaz, S. and Okay, O., Polymer, 2000, vol. 41, p. 3693.
Kabanov, V.A., Zezin, A.B., Rogacheva, V.B., and Prevysh, V.A., Dokl. Akad. Nauk SSSR, 1988, vol. 303, p. 399.
Chupyatov, A.M., Rogacheva, V.B., Zezin, A.B., and Kabanov, V.A., Vysokomol. Soedin., 1994, vol. 36, p. 212.
Boyd, G.E., Adamson, A.W., and Myerc, L.S., J. Am. Chem. Soc., 1947, vol. 69, p. 2836.
Izumrudov, V.A., Bakeev, K.N., Zezin, A.B., and Kabanov, V.A., Dokl. Akad. Nauk SSSR, 1986, vol. 286, p. 1442.
Leninger, A., Biochemistry, New York: Worth, 1975.
Shaw, R.W. and Hartzell, C.R., Biochem., 1976, vol. 15, p. 1909.
Khandurina, Yu.V., Candidate Sci. (Chem.) Dissertation, Moscow, 1993.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.A. Karpushkin, 2013, published in Ekologicheskaya Khimiya, 2013, Vol. 22, No. 2, pp. 91–98.
Rights and permissions
About this article
Cite this article
Karpushkin, E.A. Hydrogels for treatment of water polluted with macromolecules: Effect of network polyelectrolyte composition on the sorption rate. Russ J Gen Chem 83, 2731–2737 (2013). https://doi.org/10.1134/S1070363213130197
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363213130197