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Electrical and magnetic properties of nanodiamond and pyrocarbon composites

  • Supplement: Rossiiskii Khimicheskii Zhurnal-Zhurnal Rossiiskogo Khimicheskogo Obshchestva im. D.I. Mendeleeva (Russian Chemistry Journal)
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Abstract

The electrical and magnetic properties of the nanodiamond composites comprising nanodiamond, pyrolytic carbon, and nanosized pores were studied. The composites are p-type semiconductors and their resistance decreases by 12 orders of magnitude as the pyrocarbon-to-diamond ratio γ increases from 0 to 80 wt %. Evidence for paramagnetic properties of the nanodiamond composites was obtained. The observed properties are explained by increased concentration of surface Tamm states. The paramagnetic properties are explained in terms of the electron spins localized on the nanodiamond surface in the composite.

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Authors and Affiliations

  1. Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, str. 38, Krasnoyarsk, 660036, Russia

    N. I. Kiselev, D. A. Velikanov, E. A. Petrakovskaya, A. D. Vasil’ev, D. A. Balaev, O. A. Bayukov, E. V. Eremin, K. A. Shaikhutdinov, N. P. Shestakov & N. V. Volkov

  2. Central Research Institute of Materials Federal Unitary Enterprise, St. Peterburg, Russia

    S. B. Korchagina & S. K. Gordeev

  3. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia

    L. A. Solov’ev

  4. Youth Open Laboratory of Perspective Research and Technology, Institute of Biophysics, Siberian Branch, Russian Academy of Sciences, Siberian Federal University, Krasnoyarsk, Russia

    I. A. Denisov, S. S. Tsegel’nik, D. A. Znak, A. A. Shubin & P. I. Belobrov

Authors
  1. N. I. Kiselev
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  2. D. A. Velikanov
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  3. S. B. Korchagina
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  4. E. A. Petrakovskaya
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  5. A. D. Vasil’ev
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  6. L. A. Solov’ev
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  7. D. A. Balaev
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  8. O. A. Bayukov
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  9. I. A. Denisov
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  10. S. S. Tsegel’nik
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  11. E. V. Eremin
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  12. D. A. Znak
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  13. K. A. Shaikhutdinov
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  14. A. A. Shubin
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  15. N. P. Shestakov
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  16. N. V. Volkov
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  17. S. K. Gordeev
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  18. P. I. Belobrov
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Corresponding author

Correspondence to P. I. Belobrov.

Additional information

Original Russian Text © N.I. Kiselev, D.A. Velikanov, S.B. Korchagina, E.A. Petrakovskaya, A.D. Vasil’ev, L.A. Solov’ev, D.A. Balaev, O.A. Bayukov, I.A. Denisov, S.S. Tsegel’nik, E.V. Eremin, D.A. Znak, K.A. Shaikhutdinov, A.A. Shubin, N.P. Shestakov, N.V. Volkov, S.K. Gordeev, P.I. Belobrov, 2012, published in Rossiiskii Khimicheskii Zhurnal, 2012, Vol. 56, Nos. 1–2, pp. 50–57.

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Kiselev, N.I., Velikanov, D.A., Korchagina, S.B. et al. Electrical and magnetic properties of nanodiamond and pyrocarbon composites. Russ J Gen Chem 83, 2173–2181 (2013). https://doi.org/10.1134/S1070363213110376

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  • DOI: https://doi.org/10.1134/S1070363213110376

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