Abstract
The metal-exchange reaction between cadmium 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinate and zinc and copper acetates in DMF was studied. Kinetic Parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.
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Original Russian Text © S.V. Zvezdina, O.M. Kulikova, N.Zh. Mamardashvili, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 11, pp. 1912–1916.
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Zvezdina, S.V., Kulikova, O.M. & Mamardashvili, N.Z. Kinetics and mechanism of metal exchange between cadmium porphyrin complexes and d-metal salts in DMF. Russ J Gen Chem 83, 2103–2107 (2013). https://doi.org/10.1134/S1070363213110248
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DOI: https://doi.org/10.1134/S1070363213110248