Abstract
The properties of dilute solutions of styrene copolymers and their porphyrin derivatives prepared via the functional group transformations have been studied in DMF at 20–35°C. The effect of the copolymer composition, on the intrinsic viscosity, the Huggins constant, the macromolecule dimensions, and thus on the interaction with solvent has been elucidated. The nature and content of functional groups in the polymer influence the behavior of macromolecule coil in the solution. Introduction of the porphyrin fragment loosens the macromolecular coil, but does not qualitatively change the solution behavior.
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Original Russian Text © O.I. Nikolaeva, T.S. Usachev, P.A. Gorbenko, T.A. Ageeva, O.I. Koifman, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 11, pp. 1903–1911.
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Nikolaeva, O.I., Usachev, T.S., Gorbenko, P.A. et al. Viscosity of dilute solutions of styrene copolymers in the course of polymer-analogous transformations. Russ J Gen Chem 83, 2095–2102 (2013). https://doi.org/10.1134/S1070363213110236
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DOI: https://doi.org/10.1134/S1070363213110236