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Russian Journal of General Chemistry

, Volume 83, Issue 10, pp 1900–1905 | Cite as

Synthesis and properties of triphenylantimony(V) dithiolate derivative

  • S. A. Smolyaninova
  • A. I. Poddelśky
  • I. V. Smolyaninov
  • N. T. Berberova
Article

Abstract

Interaction of substituted benzene-1,2-dithiols I–III with triphenylantimony(V) dichloride was studied. As a result of the exchange reaction of 3,6-dichlorobenzene-1,2-dithiol with Ph3SbCl2 in the presence of triethylamine triphenylantimony(V) 3,6-dichlorobenzene-1,2-dithiolate IV was obtained. Electrochemical properties of the free dithiols and the complex were explored. According to the cyclic voltammetry, the oxidation of the complex is irreversible and corresponds to one electron transfer with follow-up chemical stage. The antioxidant activity of compounds I–IV was examined in the process of oleic acid autoxidation. A more effective inhibition of the oleic acid oxidation was found at adding dithiol and better protective effect was observed in the presence of Ph3SbCl2 compared with the complex IV.

Keywords

Oleic Acid Antimony Dithiol Free Radical Oxidation Thiyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • S. A. Smolyaninova
    • 1
  • A. I. Poddelśky
    • 2
  • I. V. Smolyaninov
    • 3
  • N. T. Berberova
    • 1
  1. 1.Astrakhan State Technical UniversityAstrakhanRussia
  2. 2.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhni NovgorodRussia
  3. 3.Southern Scientific Center of the Russian Academy of SciencesAstrakhanRussia

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