Abstract
A series of disubstituted p-tert-butylcalix[4]arenes with N-methoxycarbonylmonoazacrown ether and N-ethoxymonoazacrown ether residues at the lower rim has been prepared via the reaction of di(carboxymethoxy)-p-tert-butylcalix[4]arene with azacrown ethers and subsequent reduction of the resulting amide derivatives. Using UV titration and 1H NMR spectroscopy we have demonstrated the ability of the calixarene with two N-carbonylmonoaza-18-crown-6-ether substituents to form the 1:3 complexes with K+ and Na+ and the 1:2 complexes with Cs+, Sr2+, Cu2+, and Zn2+. The calixarene with two fragments of N-ethoxymonoazo-18-crown ether has formed binuclear complexes with alkali metals cations and mononuclear complexes with transition metals cations.
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Original Russian Text © E.A. Alekseeva, S.S. Basok, A.V. Mazepa, A.P. Luk’yanenko, O.V. Snurnikova, A.I. Gren’, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 9, pp. 1519–1525.
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Alekseeva, E.A., Basok, S.S., Mazepa, A.V. et al. p-tert-butylcalix[4]arenes containing azacrown ether substituents at the lower rim as potential polytopic receptors. Russ J Gen Chem 83, 1738–1743 (2013). https://doi.org/10.1134/S1070363213090181
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DOI: https://doi.org/10.1134/S1070363213090181