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Electronic effects of 2-azasilatran-3-one groups

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Abstract

1-Phenyl-2-azasilatran-3-ones have been studied by multinuclear NMR spectroscopy. The π-accepting ability of 2-azasilatran-3-one groups is substantially lower and their σ-donating ability is higher than those of (acetamido)diethoxysilyl groups of the model tetracoordinated compounds.

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Authors and Affiliations

  1. A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. F. Lazareva & I. M. Lazarev

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  1. N. F. Lazareva
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  2. I. M. Lazarev
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Correspondence to N. F. Lazareva.

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Original Russian Text © N.F. Lazareva, I.M. Lazarev, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 9, pp. 1423–1425.

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Lazareva, N.F., Lazarev, I.M. Electronic effects of 2-azasilatran-3-one groups. Russ J Gen Chem 83, 1649–1651 (2013). https://doi.org/10.1134/S1070363213090041

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