Abstract
Influence of the main process parameters on the hot wire chemical vapor deposition (HW-CVD) of polytetraethylene (PTFE) films in the hexafluoropropylene (HFPO)-argon system at low pressure as well as the gas flow structure in the reactor and its effect on the precursor conversion was evaluated. It was found out that that the conversion reaches ∼90% at the hot wire temperature above 800°C, increases ∼5.5 times with the increase in pressure from 7.5 to 35 Pa and decreases twice with the increase of precursor flow from 8 to 33 ml min−1. It was shown that the process parameters affect significantly the gas residence time and average temperature, and also the intensity of gas flow recirculation in the reactor.
Similar content being viewed by others
References
Panshin, Yu.A., Malkevich, S.G., and Dunaevskaya, Ts.S., Ftoroplasty (Fluoroplastics), Leningrad: Khimiya, 1978.
McKeen, L.W., Fluoronated Coatings and Finishes Handbook, New York: William Andrew Publishing, 2006.
Panneman, C., Diekmann, T., Hilleringmann, U., Schurmann, U., Scharnberg, M., Zaporojchenko, V. and Adelung, R., Faurel F., Mat. Sci. (Poland), 2007, vol. 25, p. 95.
Oya, T. and Kusano, E., Vacuum, 2008, vol. 83, no. 3, p. 564.
Schwodiauler, R., Heintz, J., and Arenholz, E., J. Polym Sci., B, 1999, vol. 37, no. 16, p. 2115.
Liua, D., Gua, J., Feng, Z., Li, D., Niu, J., and Benstetter, G., Vacuum, 2010, vol. 85, no. 2, p. 253.
Limb, S.J., Labelle, C.B., Gleason, K.K., Edell, D.J., and Gleason, E.F., Appl. Phys. Lett., 1996, vol. 68, p. 2810.
Safonov, A.I., J. Appl. Mech. Tech. Phys., 2011, vol. 52, no. 3, p. 496.
Zhou, J., Overmeyer, A., and Wolden, C.A., Proc. Electrochem. Soc., 2001, vol. 3, p. 92.
Uvarov, A., Uemura, K., Alexandrov, S., Murayama, H. and Soba, R., Proc. of 10th Int. Conf. “Modification of Materials with Particle Beams and Plasma Flows,” Tomsk, 2010, p. 500.
Uvarov, A.A. and Aleksandrov, S.E., NTV SPbGPU, 2011, no. 3, p. 141.
Dunyakhin, V.A., Timofeev, V.V., and Zhitnev, Yu.N., Russ. Chem. Bull., 1995, vol. 43, no. 11, p. 1816.
Thermodynamic Properties of HFC-134a, [Electronic resource]/ Du Pont, 2004, access regime: http://2.dupont.com/Refrigerants/en-US/assets/downloads, free — English language, call date 10.037.2013.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Uvarov, S.E. Aleksandrov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 8, pp. 1378–1383.
Rights and permissions
About this article
Cite this article
Uvarov, A.A., Aleksandrov, S.E. Specific features of chemical deposition of polytetrafluoroethylene films from hexafluoropropylene oxide. Russ J Gen Chem 83, 1607–1612 (2013). https://doi.org/10.1134/S1070363213080239
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363213080239