Abstract
The observed featured and regularities of nucleophilic substitution of chlorine in poly(vinyl chloride) upon its reaction with sodium and potassium derivatives of pyrazole, 3,5-dimethylpyrazole, and 2-thiobenzimidazole, and with sodium thiophenolate have been understood in the frame of hard and soft acids and bases theory.
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Original Russian Text © N.S. Shaglaeva, M.G. Voronkov, V.V. Bayandin, R.G. Sultangareev, G.F. Prozorova, K.A. Abzaeva, E.A. Orkhokova, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 8, pp. 1286–1293.
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Shaglaeva, N.S., Voronkov, M.G., Bayandin, V.V. et al. Poly(vinyl chloride) reactions with sodium and potassium derivatives of heteroaromatic and aromatic NH- and SH-acids in aprotic solvents. Russ J Gen Chem 83, 1519–1525 (2013). https://doi.org/10.1134/S1070363213080082
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DOI: https://doi.org/10.1134/S1070363213080082