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Study of acidity and coordination properties of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in the system of 1,8-diazabicyclo[5.4.0]undec-7-ene-acetonitrile

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Abstract

Spectrophotometric titration method was used to study the acidic properties of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in the presence of a deprotonated agent, 1,8-diazabicyclo[5.4.0] undec-7-ene, in acetonitrile. The spectral characteristics of the ionized forms and combined ionization constant for the first and second stages were revealed. The reaction of complex formation between the dianionic forms of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and zinc acetate was studied.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. B. Ivanova

  2. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    S. G. Pukhovskaya, A. S. Semeikin & S. A. Syrbu

Authors
  1. Yu. B. Ivanova
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  2. S. G. Pukhovskaya
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  3. A. S. Semeikin
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  4. S. A. Syrbu
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Correspondence to S. G. Pukhovskaya.

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Original Russian Text © Yu.B. Ivanova, S.G. Pukhovskaya, A.S. Semeikin, S.A. Syrbu, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 7, pp. 1156–1159.

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Ivanova, Y.B., Pukhovskaya, S.G., Semeikin, A.S. et al. Study of acidity and coordination properties of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in the system of 1,8-diazabicyclo[5.4.0]undec-7-ene-acetonitrile. Russ J Gen Chem 83, 1406–1409 (2013). https://doi.org/10.1134/S1070363213070177

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  • DOI: https://doi.org/10.1134/S1070363213070177

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