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Synthesis, structure, and properties of a new phosphorus-containing Schiff’s base, a derivative of pyrazole-5-one

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Abstract

A new Schiff’s base and its salt have been prepared from 2-aminophenyl(triphenyl)phosphonium chloride and 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. The products structures have been proved by IR, 1H NMR, and UV spectroscopy, mass spectrometry, X-ray diffraction analysis, and quantum-chemical modeling. Possible tautomerism and some properties of the products have been studied.

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Correspondence to S. A. Borodkin.

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Original Russian Text © L.D. Popov, S.A. Borodkin, I.N. Scherbakov, Yu.N. Tkachenko, G.G. Aleksandrov, S.S. Beloborodov, A.A. Zubenko, V.A. Kogan, O.V. Maevskii, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 7, pp. 1125–1131.

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Popov, L.D., Borodkin, S.A., Scherbakov, I.N. et al. Synthesis, structure, and properties of a new phosphorus-containing Schiff’s base, a derivative of pyrazole-5-one. Russ J Gen Chem 83, 1376–1382 (2013). https://doi.org/10.1134/S107036321307013X

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  • DOI: https://doi.org/10.1134/S107036321307013X

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