Skip to main content
Log in

Physicochemical properties of 1,2-diacylhydrazines based on α-branched tertiary carboxylic acids Versatic

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

New 1,2-diacylhydrazines based on higher α-branched tertiary carboxylic acids Versatic-10 were prepared. Taking into consideration the possible application of these reagents in the processes of heterophase separation of nonferrous metal ions the physicochemical properties of the reagents were examined: the solubility, the stability against hydrolysis, thermal stability. The values of the constants of acid dissociation pK a1 and pK a2 and the protonation constant pK prot were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Radushev, A.V., Zubareva, G.I., and Chekanova, L.G., Izv. Vuzov., Ser. Metallurgiya, 1999, no. 2, p. 3.

    Google Scholar 

  2. Chekanova, L.G., Radushev, A.V., Lesnov, A.E., and Sazonova, E.A., Zh. Obshch. Khim., 2002, vol. 72, no. 8, p. 1315.

    Google Scholar 

  3. Bernshtein, I.Ya. and Kaminskii, Yu.L., Spektrofotometricheskii analiz v organicheskoi khimii (Spectrophotometric Analysis in Organic Chemistry), Leningrad: Khimiya, 1986, p. 116.

    Google Scholar 

  4. Grekov, A.P. and Sukhorukova, G.A., Polimery na osnove gydrazina (Polymers based on Hydrazine), Kiev: Naukova Dumka, 1976, p. 23.

    Google Scholar 

  5. Radushev, A.V., Batueva, T.D., and Gusev, V.Yu., Zh. Obshch. Khim., 2006, vol. 76, no. 8, p. 1246.

    Google Scholar 

  6. Radushev, A.V., Chekanova, L.G., Gusev, V.Yu., and Sazonova, E.A., Zh. Analit. Khim., 2000, vol. 55, no. 5, p. 496.

    Google Scholar 

  7. Gordon, A.J. and Ford, R.A., The Chemist’s Companion. A Handbook of Practical Data, Techniques and References, New York: Wiley, 1972.

    Google Scholar 

  8. Radushev, A.V., Vaulina, V.N., and Gusev, V.Yu., Zh. Analit. Khim., 2010, vol. 65, no. 8, p. 831.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Radushev.

Additional information

Original Russian Text © A.V. Radushev, T.D. Batueva, A.V. Kataev, A.A. Gorbunov, L.G. Chekanova, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 7, pp. 1057–1060.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Radushev, A.V., Batueva, T.D., Kataev, A.V. et al. Physicochemical properties of 1,2-diacylhydrazines based on α-branched tertiary carboxylic acids Versatic. Russ J Gen Chem 83, 1311–1314 (2013). https://doi.org/10.1134/S1070363213070013

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363213070013

Keywords

Navigation