Abstract
The problems concerning the formation of complexes with proton transfer of β-substituted β,β-fused tetraazaporphyrins in a system dimethyl sulfoxide-chlorobenzene (benzene) are considered. The problems of their structure are discussed. The reactivity of the proton-transfer tetraazaporphyrin complexes in the reaction with metal acetates was studied. The stability of the proton-transfer tetraazaporphyrin complexes depending on the basicity of the environment and the nature of the substituents in the macrocycle is analyzed.
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Original Russian Text © O.A. Petrov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 6, pp. 1006–1012.
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Petrov, O.A. Proton-transfer complexes of β-substituted β,β-fused tetraazaporphyrins. Russ J Gen Chem 83, 1136–1142 (2013). https://doi.org/10.1134/S1070363213060224
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DOI: https://doi.org/10.1134/S1070363213060224