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Supramolecular chelate copper(II) complex with 4-[(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1Hpyrazol-3(2H)-one: Synthesis, crystal structure, and properties

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Abstract

A supramolecular Cu(II) complex, [Cu(L)2(H2O)]·C2H5OH {HL = 4-[(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one]} was synthesized and characterized structurally. The structure of the Cu(II) complex consists of one Cu(II) atom, two bidentate L-units, one coordinated H2O and one crystallization ethanol molecule. The Cu(II) atom of the complex has a slightly distorted tetragonal pyramidal geometry. Moreover, every Cu(II) complex molecule links four other molecules into an infinite 2D-layer supramolecular structure via intermolecular O-H…O, O-H…N, and C-H…O hydrogen bonds.

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Authors and Affiliations

  1. Lanzhou Jiaotong University, West Anning Road 88, Lanzhou, 730070, P. R. China

    W. -K. Dong, G. Wanga, Y. -X. Sun, X. -Y. Dong, J. Yao & X. -H. Gaob

  2. Lanzhou Petrochemical Research Center, PetroChina, Lanzhou, P. R. China

    W. -K. Dong, G. Wanga, Y. -X. Sun, X. -Y. Dong, J. Yao & X. -H. Gaob

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  1. W. -K. Dong
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  2. G. Wanga
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  3. Y. -X. Sun
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  4. X. -Y. Dong
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  5. J. Yao
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  6. X. -H. Gaob
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Correspondence to X. -Y. Dong.

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Original Russian Text © W.-K. Dong, G. Wanga, Y.-X. Sun, X.-Y. Dong, J. Yao, X.-H. Gaob, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 6, pp. 1001–1005.

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Dong, W.K., Wanga, G., Sun, Y.X. et al. Supramolecular chelate copper(II) complex with 4-[(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1Hpyrazol-3(2H)-one: Synthesis, crystal structure, and properties. Russ J Gen Chem 83, 1131–1135 (2013). https://doi.org/10.1134/S1070363213060212

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  • DOI: https://doi.org/10.1134/S1070363213060212

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