Abstract
Hydrates of Eu(III) and Tb(III) salts with anions (L) 4-CF3C6F4COO− and 4-(CF3)2CFC6F4COO−, and also mixed-ligand complexes Ln(phen)(L)3 were obtained. The compounds show red and green photoluminescence characteristic of Eu3+ and Tb3+ ions, respectively, in the visible region of spectrum. The intensity of the photoluminescence of the complexes containing 1,10-phenanthroline is much higher than that of compounds containing water. It is connected with sensitizing properties of phen in relation to Eu3+ and Tb3+ ions.
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Original Russian Text © S.V. Larionov, T.G. Leonova, E.M. Uskov, M.I. Rakhmanova, V.E. Platonov, V.M. Karpov, V.P. Fadeeva, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 6, pp. 986–991.
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Larionov, S.V., Leonova, T.G., Uskov, E.M. et al. Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)2CFC6F4COOH acids. Russ J Gen Chem 83, 1117–1122 (2013). https://doi.org/10.1134/S1070363213060194
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DOI: https://doi.org/10.1134/S1070363213060194