Russian Journal of General Chemistry

, Volume 83, Issue 6, pp 1111–1116 | Cite as

Synthesis of new spiropyranes and study of the effect of the nature of substituents on their photochromism and complexation

  • L. D. Popov
  • A. O. Bulanov
  • E. A. Raspopova
  • A. N. Morozov
  • I. N. Scherbakov
  • O. I. Kobeleva
  • T. M. Valova
  • V. A. Barachevskii
Article

Abstract

A series of new hydrazones based on 3,3-dimethyl-7-hydroxy-8-formyl-[2H]-1-benzopyran-2,1-[2]-oxaindane] with the substituents of different nature in the hydrazone moiety was synthesized. A comparative study of photochromism and complexation of the synthesized spiropyrans with a number of metal cations was carried out. Spectral and kinetic differences in photochromism and complexation of these compounds were revealed.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • L. D. Popov
    • 1
  • A. O. Bulanov
    • 1
  • E. A. Raspopova
    • 1
  • A. N. Morozov
    • 1
  • I. N. Scherbakov
    • 1
  • O. I. Kobeleva
    • 2
  • T. M. Valova
    • 2
  • V. A. Barachevskii
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Photochemistry CenterRussian Academy of SciencesMoscowRussia

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