Abstract
The formation by 1H-1,2,4-triazoline-3-thiones in dilute chloroform solution of n-σ*-complex with molecular iodine of the composition C2H2N3S·I2 was studied by electronic spectroscopy in the UV and visible regions (log β = 2.14±0.05). By the XRD method the crystal and molecular structure of the product of chemical interaction of the thione with molecular iodine in ethanol, 1,2-di(1H-1,2,4-triazol-3-yl) disulfide, was determined.
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Original Russian Text © M.S. Chernovyants, N.V. Aleshina, I.N. Shcherbakov, Z.A. Starikova, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 5, pp. 852–854.
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Chernovyants, M.S., Aleshina, N.V., Shcherbakov, I.N. et al. Spectroscopic study of interaction of 1H-1,2,4-triazoline-3-thione with molecular iodine. Russ J Gen Chem 83, 986–988 (2013). https://doi.org/10.1134/S1070363213050186
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DOI: https://doi.org/10.1134/S1070363213050186