Abstract
On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX2 salts (X = Cl, Br, I, NCS) with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine (I), piperidine (II), and piperazine (III) the nature of acido-ligands influence on catalase activity of complexes I–III was revealed, depending on the structure and composition of the chelating ligand. Mononuclear complexes I(Br) and II(Br) can transform into 10-membered binuclear macrochelate intermediates.
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Original Russian Text © D.G. Chihichin, V.A. Kotseruba, O.A. Levchenko, G.N. Masanovets, I.I. Seyfullina, G.L. Kamalov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 5, pp. 778–790.
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Chihichin, D.G., Kotseruba, V.A., Levchenko, O.A. et al. Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides. Russ J Gen Chem 83, 915–927 (2013). https://doi.org/10.1134/S107036321305006X
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DOI: https://doi.org/10.1134/S107036321305006X