Abstract
A number of β-phenyl(or benzyl)selanyl- and β-phenylsulfanyl-substituted imines possessing an additional donor nitrogen, oxygen, or sulfur atom were synthesized by reaction of 2-phenylsulfanylethanamine, 2-phenylsulfanylcyclohexanamine, 2-phenylselanylcyclohexanamine, and 2-benzylselanylaniline with salicylaldehyde, 2-pyridinecarbaldehyde, or 2-tert-butylsulfanylbenzaldehyde. The resulting Schiff bases were tested as ligands in the complex formation with nickel(II) and copper(II), and mononuclear (L-H)MCl or LMCl2 coordination compounds were isolated (L = sulfur- or selenium-containing imine). The redox properties of the selenium-containing ligands and complexes were studied by cyclic voltammetry. The complexes were found to undergo reduction of the metal ion in two one-electron steps. The reduction is reversible for copper complexes and irreversible for nickel complexes.
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Original Russian Text © A.N. Chernysheva, E.K. Beloglazkina, R.L. Antipin, A.A. Moiseeva, N.V. Zyk, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 2, pp. 257–264.
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Chernysheva, A.N., Beloglazkina, E.K., Antipin, R.L. et al. New sulfanyl- and selanyl-substituted Schiff bases derived from 2-chalcogenoalkylamines and aromatic aldehydes. Synthesis and complex formation reactions. Russ J Gen Chem 83, 311–318 (2013). https://doi.org/10.1134/S1070363213020138
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DOI: https://doi.org/10.1134/S1070363213020138