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Reaction of vanadocene and vanadocene dichloride with ortho-iodobenzoic acid

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Abstract

At the interaction of bis (η5-cyclopentadienyl)vanadium with iodobenzoic acid or trimethylsilyl o-iodobenzoate in toluene depending on the ratio of the initial reagents bis(η5-cyclopentadienyl)vanadium(o-iodobenzoate) or η5-cyclopentadienylvanadium-bis-o-iodobenzoate were obtained in high yields. The latter was also formed in the reaction of bis(η5-cyclopentadiene)vanadium dihloride with trimethylsilyl o-iodobenzoate.

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Correspondence to A. S. Gordetsov.

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Original Russian Text © A.S. Gordetsov, S.V. Zimina, V.F. Ur’yash, E.M. Moseeva, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 2, pp. 245–248.

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Gordetsov, A.S., Zimina, S.V., Ur’yash, V.F. et al. Reaction of vanadocene and vanadocene dichloride with ortho-iodobenzoic acid. Russ J Gen Chem 83, 299–302 (2013). https://doi.org/10.1134/S1070363213020114

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  • DOI: https://doi.org/10.1134/S1070363213020114

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