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Study of intermolecular interaction of Mg-5,15-Di(o-methoxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetrabutylporphin with o-xylene organic peroxides. Effect of imidazole on the reaction kinetics

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Abstract

Using the method of spectrophotometric titration a reaction of magnesium porphyrinate with the o-xylene organic peroxides was investigated, the reaction mechanism and kinetic parameters were determined. The effect of imidazole on the rate of the reaction under investigation was demonstrated. The presence of steric strain in the magnesium porphyrinate macrocycle and its increase in the course of formation of intermediates was observed.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. R. Simonova, S. V. Zaitseva & O. I. Koifman

  2. Ivanovo State University of Chemical Tehnology, Ivanovo, Russia

    O. I. Koifman

Authors
  1. O. R. Simonova
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  2. S. V. Zaitseva
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  3. O. I. Koifman
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Correspondence to O. R. Simonova.

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Original Russian Text © O.R. Simonova, S.V. Zaitseva, O.I. Koifman, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 1, pp. 118–123.

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Simonova, O.R., Zaitseva, S.V. & Koifman, O.I. Study of intermolecular interaction of Mg-5,15-Di(o-methoxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetrabutylporphin with o-xylene organic peroxides. Effect of imidazole on the reaction kinetics. Russ J Gen Chem 83, 110–115 (2013). https://doi.org/10.1134/S1070363213010192

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  • DOI: https://doi.org/10.1134/S1070363213010192

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