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Structural parameters of the close environment of group III metal ions in aqueous solutions of their salts

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Abstract

Published data obtained by various research methods and our own experimental results on the structural characteristics of the nearest environment of aluminum, gallium, indium, thallium, as well as scandium, yttrium and lanthanum ions in aqueous solutions of their salts under ambient conditions are summarized. The structural parameters, like coordination number, interparticle distance, parameters of the second coordination sphere and the types of ion association are discussed. The hydrate complexes of the ions of aluminum and gallium subgroups are compared.

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References

  1. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2006, vol. 76, no. 2, p. 187.

    Google Scholar 

  2. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2007, vol. 77, no. 12, p., 1955.

  3. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2008, vol. 78, no. 9, p. 1409.

    Google Scholar 

  4. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2009, vol. 79, no. 8, p. 1242.

    Google Scholar 

  5. Marcus, Y., Chem. Rev., 1988, vol. 88, no. 8, p. 1475.

    Article  CAS  Google Scholar 

  6. Ohtaki, H. and Radnai, T., Chem. Rev., 1993, vol. 93, no. 3, p. 1157.

    Article  CAS  Google Scholar 

  7. Gauthier, E., Fortier, I., Courchesne, F., Pepin, P., Mortimer, J., and Gauvreau, D., Environ. Res., 2000, vol. 84, no. 3, p. 234.

    Article  CAS  Google Scholar 

  8. Fiat, D. and Connick, R.E., J. Am. Chem. Soc., 1968, vol. 90, no. 3, p. 608.

    Article  CAS  Google Scholar 

  9. Hugi-Cleary, D., Helm, L., and Merbach, A.E., Helv. Chim. Acta, 1985, vol. 68, no. 3, p. 545.

    Article  CAS  Google Scholar 

  10. Connick, R.E. and Fiat, D.N., J. Chem. Phys., 1963, vol. 39, no. 5, p. 1349.

    Article  CAS  Google Scholar 

  11. Alei, M. and Jackson, J.A., J. Chem. Phys., 1964, vol. 41, no. 11, p. 3402.

    Article  CAS  Google Scholar 

  12. Schuster, R.E. and Fratiello, A., J. Chem. Phys., 1967, vol. 47, no. 4, p. 1554.

    Article  CAS  Google Scholar 

  13. Fratiello, A., Lee, R.E., Nishida, V.M., and Schuster, R.E., J. Chem. Phys., 1968, vol. 48, no. 8, p. 3705.

    Article  CAS  Google Scholar 

  14. Matwiyoff, N.A., Darley, P.E., and Movius, W.G., Inorg. Chem., 1968, vol. 7, no. 10, p. 2173.

    Article  CAS  Google Scholar 

  15. Bol, W. and Welzen, T., Chem. Phys. Lett., 1977, vol. 49, no. 1, p. 189.

    Article  CAS  Google Scholar 

  16. Caminiti, R., Licheri, G., Piccaluga, G., Pinna, G., and Radnai, T., J. Chem. Phys., 1979, vol. 71, no. 6, p. 2473.

    Article  CAS  Google Scholar 

  17. Caminiti, R. and Radnai, T., Z. Naturforsch. A, 1980, vol. 35, no. 12, p. 1368.

    Google Scholar 

  18. Kanno, H., J. Phys. Chem., 1988, vol. 92, no. 14, p. 4232.

    Article  CAS  Google Scholar 

  19. Alves Marques, M., Sousa Oliveira MA., and Resina Rodrigues, J., J. Chem. Soc., Faraday Trans., 1990, vol. 86, no. 3, p. 471.

    Article  CAS  Google Scholar 

  20. Hermansson, K., Olovsson, I., and Lunell, S., Theor. Chim. Acta, 1984, vol. 64, no. 4, p. 265.

    Article  CAS  Google Scholar 

  21. Probst, M.M., J. Mol. Struct., 1990, vol. 208, nos. 1–2, p. 45.

    Google Scholar 

  22. Marcos, E.S., Pappalardo, R.R., and Rinaldi, D., J. Phys. Chem., 1991, vol. 95, no. 22, p. 8928.

    Article  Google Scholar 

  23. Floris, F., Persico, M., Tani, A., and Tomasi, J., Chem. Phys., 1995, vol., 195, no. 1–3, p. 207.

    Article  CAS  Google Scholar 

  24. Wasserman, E., Rustad, J.R., and Xantheas, S.S., J. Chem. Phys., 1997, vol. 106, no. 23, p. 9769.

    Article  CAS  Google Scholar 

  25. Bakker, A., Hermansson, K., Lindgren, J., Probst, M.M., and Bopp, P.A., Int. J. Quantum Chem., 1999, vol. 75, nos. 4–5, p. 659.

    Article  CAS  Google Scholar 

  26. Martinez, J.M., Pappalardo, R.R., and Marcos, E.S., J. Am. Chem. Soc., 1999, vol. 121, no. 13, p. 3175.

    Article  CAS  Google Scholar 

  27. Lubin, M.I., Bylaska, E.J., and Weare, J.H., Chem. Phys. Lett., 2000, vol. 322, no. 6, p. 447.

    Article  CAS  Google Scholar 

  28. Lauenstein, A., Hermansson, K., Lindgren, J., Probst, M., and Bopp, P.A., Int. J. Quantum Chem., 2000, vol. 80, nos. 4–5, p. 892.

    Article  CAS  Google Scholar 

  29. Ikeda, T., Hirata, M., and Kimura, T., J. Chem. Phys., 2003, vol. 119, no. 23, p. 12386.

    Article  CAS  Google Scholar 

  30. Spangberg, D., and Hermansson, K., J. Chem. Phys., 2004, vol. 120, no. 10, p. 4829.

    Article  CAS  Google Scholar 

  31. Hofer, T.S., Randolf, B.R., and Rode, B.M., Phys. Chem. Chem. Phys., 2005, vol. 7, p. 1382.

    Article  CAS  Google Scholar 

  32. Amira, S., Spangberg, D., and Hermansson, K., J. Chem. Phys., 2006, vol. 124, no. 10, p. 104501.

    Article  Google Scholar 

  33. Bylaska, E.J., Valiev, M., Rustad, J.R., and Weare, J.H., J. Chem. Phys., 2007, vol. 126, no. 10, p. 104505.

    Article  Google Scholar 

  34. Hofer, T.S., Randolf, B.R., and Rode, B.M., J. Phys. Chem. (B), 2008, vol. 112, no. 37, p. 11726.

    CAS  Google Scholar 

  35. Faro, T.M., Thim, G.P., and Skaf MS., J. Chem. Phys., 2010, vol. 132, no. 11, p. 114509.

    Article  Google Scholar 

  36. Rudolph, W.W, Mason, R., and Pye, C.C., Phys. Chem. Chem. Phys., 2000, vol. 2, no. 22, p. 5030.

    Article  CAS  Google Scholar 

  37. Hay MB. and Myneni, S.C.B., J. Phys. Chem. (A), 2008, vol. 112, no. 42, p. 10595.

    Article  CAS  Google Scholar 

  38. Sakuma, T., Hoshino, S., and Fujii, Y., Solid State Commun., 1978, vol. 25, no. 2, p. 145.

    Article  CAS  Google Scholar 

  39. Bergstrom, P.A., Lindgren, J., Read, M., and Sandsrtsm, M., J. Phys. Chem., 1991, vol. 95, no. 20, p. 7650.

    Article  Google Scholar 

  40. Bock, C.W., Markham, G.D., Katz, A.K., and Glusker, J.P., Inorg Chem., 2003, vol. 42, no. 5, p. 1538.

    Article  CAS  Google Scholar 

  41. Waluyo, I., Huang, C., Nordlund, D., Bergmann, U., Weiss, T.M., Pettersson, L.G.M., and Nilsson, A., J. Chem. Phys., 2011, vol. 134, no. 6, p. 064513.

    Article  Google Scholar 

  42. Irish, D.E., Chang, G., and Nelson, D., L., Inorg. Chem., 1970, vol. 9, no. 2, p. 425.

    Article  CAS  Google Scholar 

  43. Miceli, J. and Stuehr, J., J. Am. Chem. Soc., 1968, vol. 90, no. 25, p. 6967.

    Article  CAS  Google Scholar 

  44. Stryker, L.J. and Matijevic, E., J. Phys. Chem., 1969, vol. 73, no. 5, p. 1484.

    Article  CAS  Google Scholar 

  45. Bonsen, A. and Knoch, W., Ber. Bunsen. Phys. Chem., 1978, vol. 82, no. 7, p. 678.

    Article  CAS  Google Scholar 

  46. Akitt, J.W. and Faznsworth, J.A., J. Chem. Soc., Faraday Trans. 1, 1985, vol. 81, p. 193.

    Article  CAS  Google Scholar 

  47. Schrödle, S., Rudolph, W.W., Hefter, G., and Buchner, R., Geochim. Cosmochim. Acta, 2007, vol. 71, no. 22, p. 5287.

    Article  Google Scholar 

  48. Valeev, A.Kh., Smirnov, P.R., Trostin, V.N., and Krestov, G.A., Zh. Obshch. Khim., 1989, vol. 59, no. 11, p. 2421.

    CAS  Google Scholar 

  49. Kirilenko, I.A., Kuznetsov, V.V., and Trostin, V.N., Dokl. Akad. Nauk SSSR, 1988, vol. 298, no. 1, p. 159.

    CAS  Google Scholar 

  50. Gaspar, A.M., Alves Marques, M., Cabaço, M.I., de Barros Marques, M.I., Kolesnikov, A.I., Tomkinson, J., and Li, J.-C., J. Phys.: Condens. Matter., 2004, vol. 16, no. 36, p. 6343.

    Article  CAS  Google Scholar 

  51. Smirnov, P.R., Trostin, V.N., and Yamaguchi, T., Zh. Fiz. Khim., 2006, vol. 80, no. 1, p. 94.

    Google Scholar 

  52. Da-Silva, C., Proux, O., Hazemann, J.-L., James-Smith, J., Testemale, D., and Yamaguchi, T., J. Mol. Liq., 2009, vol. 147, nos. 1-2, p. 83.

    Article  Google Scholar 

  53. Maeda, M. and Ohtaki, H., Bull. Chem. Soc. Japan., 1977, vol. 50, no. 7, p. 1893.

    Article  CAS  Google Scholar 

  54. Caminiti, R. and Paschina, G., Chem. Phys. Lett., 1981, vol. 82, no. 3, p. 487.

    Article  CAS  Google Scholar 

  55. Caminiti, R., Johansson, G., and Toth, I., Acta Chem. Scand. (A), 1986, vol. 40, p. 435.

    Article  Google Scholar 

  56. Alves Marques, M., and Cabaco, M.I., Chem. Phys. Lett., 1986, vol. 123, no. 1–2, p. 73.

    Article  CAS  Google Scholar 

  57. Alves Marques, M., Cabaco, M.I., and Sausa Olivera, M.A., Chem. Phys. Lett., 1986, vol. 126, no. 6, p. 551.

    Article  CAS  Google Scholar 

  58. Lindqvist-Reis, P., Munoz-Paez, A., Diaz-Moreno, S., Pattanaik, S., Persson, I., and Sandstrtsm, M., Inorg. Chem., 1998, vol. 37, no. 26, p. 6675.

    Article  CAS  Google Scholar 

  59. Seward, T.M., Henderson, C.MB., and Charnock, J.M., Chem. Geology, 2000, vols. 1–2, p. 117.

    Article  Google Scholar 

  60. Alves Marques, M., Oliveira MA.S., Resina Rodrigues, J., Cavagnat, R.M., and Devaure, J., J. Chem. Soc., Faraday Trans., 1990, vol. 86, no. 23, p. 3883.

    Article  Google Scholar 

  61. Rudolph, W.W., Fischer, D., Tomney MR., and Pye, C.C., Phys. Chem. Chem. Phys., 2004, vol. 6, no. 22, p. 5145.

    Article  CAS  Google Scholar 

  62. Glaser, J., Acta Chem. Scand. (A), 1982, vol. 36, p. 451.

    Article  Google Scholar 

  63. Glaser, J. and Johansson, G., Acta Chem. Scand. (A), 1981, vol. 35, p. 639.

    Article  Google Scholar 

  64. Glaser, J. and Johansson, G., Acta Chem. Scand. (A), 1982, vol. 36, no. 2, p. 125.

    Article  Google Scholar 

  65. Blixt, J., J. Am. Chem. Soc., 1995, vol. 117, no. 18, p. 5089.

    Article  CAS  Google Scholar 

  66. Vchirawongkwin, V., Hofer, T.S., Randolf, B.R., and Rode, B.M., J. Comput. Chem., 2007, vol. 28, no. 6, p. 1057.

    Article  CAS  Google Scholar 

  67. Rudolph, W.W. and Pye, C.C., J. Phys. Chem. (A), 2000, vol. 104, no. 8, p. 1627.

    Article  CAS  Google Scholar 

  68. Rudolph, W.W. and Pye, C.C., J. Solut. Chem., 2000, vol. 29, no. 10, p. 955.

    Article  CAS  Google Scholar 

  69. Tarasov, V.P., Kirakosyan, G.A., Trots, S.V., Buslaev, Yu.A., and Panyushkin, V.T., Koord. Khim, 1983, vol. 9, no. 2, p. 205.

    CAS  Google Scholar 

  70. Kirakosyan, G.A. and Tarasov, V.P., Koord. Khim, 1982, vol. 8, no. 2, p. 261.

    CAS  Google Scholar 

  71. Kanno, H. and Yoshimura, Y., J. Alloys Comp., 1995, vol. 225, nos. 1–2, p. 253.

    Article  CAS  Google Scholar 

  72. Yamaguchi, T., Niihara, M., Takamuku, T., Wakita, H. and Kanno, H., Chem. Phys. Lett., 1997, vol. 274, nos. 5–6, p. 485.

    Article  CAS  Google Scholar 

  73. Kanno, H., Yamaguchi, T., and Ohtaki, H., J. Phys. Chem., 1989, vol. 93, no. 5, p. 1695.

    Article  CAS  Google Scholar 

  74. Castellani, C.B., Carugo, O., Giusti, M., and Sardone, N., Eur. J. Solid State Inorg. Chem., 1995, vol. 32, p. 1089.

    CAS  Google Scholar 

  75. Lindqvist-Reis, P., Persson, I., and Sandström, M., Dalton Trans., 2006, vol. 32, p. 3868.

    Article  Google Scholar 

  76. Smirnov, P., Wakita, H., and Yamaguchi, T., J. Phys. Chem., 1998, vol. 102, no. 24, p. 4802.

    CAS  Google Scholar 

  77. Johansson, G. and Wakita, H., Inorg. Chem., 1985, vol. 24, no. 19, p. 3047.

    Article  CAS  Google Scholar 

  78. Johansson, G., Niinisto, L., and Wakita, H., Acta Chem. Scand. (A), 1985, vol. 39, no. 5, p. 359.

    Article  Google Scholar 

  79. Matsubara, E., Okuda, K., and Waseda, Y., J. Phys.: Condens. Matter., 1990, vol. 2, no. 46, p. 9133.

    Article  CAS  Google Scholar 

  80. De Barros Marques, M.I., Alves Marques, M., and Rodrigues, J.R., J. Phys.: Condens. Matter., 1992, vol. 4, no. 38, p. 7679.

    Article  Google Scholar 

  81. Isabel Cabaco, M., Alves Marques, M., De Barros Marques, M.I., and Bushnell-Wye, G., J. Phys.: Condens. Matter, 1995, vol. 7, no. 38, p. 7409.

    Article  Google Scholar 

  82. Ragnarsdottir, K.V., Oelkers, E.H., Sherman, D.M., and Collins, C.R., Chem. Geology, 1998, vol. 151, nos. 1–4, p. 29.

    Article  Google Scholar 

  83. Lindqvist-Reis, P., Lamble, K., Pattanaik, S., Persson, I., and Sandström, M., J. Phys. Chem., 2000, vol. 104, no. 2, p. 402.

    CAS  Google Scholar 

  84. Diaz-Moreno, S., Munoz-Paez, A., and Chaboy, J., J. Phys. Chem. (A), 2000, vol. 104, no. 6, p. 1278.

    Article  CAS  Google Scholar 

  85. Ramos, S., Neilson, G.W., Barnes, A.C., and Mazuelas, A., J. Phys. Chem. (B), 2001, vol. 105, no. 14, p. 2694.

    CAS  Google Scholar 

  86. Cabazo, M.I., de Barros Marques, M.I., Alves Marques, M., Gaspar, A.M., and Almeida, M.L., J. Mol. Liq., 2005, vol. 117, nos. 1–3, p. 69.

    Google Scholar 

  87. Ikeda, T., Hirata, M., and Kimura, T., J. Chem. Phys., 2005, vol. 122, no. 2, p. 024510.

    Article  Google Scholar 

  88. Ikeda, T., Hirata, M., and Kimura, T., J. Chem. Phys., 2005, vol. 122, no. 24, p. 244507.

    Article  Google Scholar 

  89. Bowron, D.T., Diaz-Moreno, S., J. Phys. Chem. (B), 2007, vol. 111, no. 39, p. 11393.

    CAS  Google Scholar 

  90. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2012, vol. 82, no. 3, p. 366.

    Google Scholar 

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  1. Krestov Institute of Solution Chemistry, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    P. R. Smirnov & V. N. Trostin

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Original Russian Text © P.R. Smirnov, V.N. Trostin, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 1, pp. 18–28

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Smirnov, P.R., Trostin, V.N. Structural parameters of the close environment of group III metal ions in aqueous solutions of their salts. Russ J Gen Chem 83, 15–25 (2013). https://doi.org/10.1134/S1070363213010039

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