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2,4,6-triaminopyrimidine and its associates with bis(hydroxymethyl)phosphinic acid. State in solution, protolytic, and complexing properties

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Abstract

Protolytic and complexing properties of 2,4,6-triaminopyrimidine and its associates with bis (hydroxymethyl)phosphinic acid in aqueous solution were studied using pH measurements, spectrophotometry (298 K), and mathematical simulation of equilibria (CPESSP software). The stability constants of the associates formed in solution were calculated. It was found that the said associates and the nitrogen base in their composition did not form innner-sphere complexes with typical complexing agents like doubly charged cations of d-elements and lanthanum(III). 2,4,6-Triaminopyrimidine forms an outer-sphere complex with copper(II) ions to affording tetrachlorocuprate(II) with diprotonated 2,4,6-triaminopyrimidine.

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References

  1. Fattakhov, S.G., Mingaleev, D.N., Safin, M.A., Reznik, V.S., Zalyalov, I.N., Tremasov, M.Ya., Konovalov, A.I., and Vizel’, A.A., RF Patent 2281939, 2006.

  2. Fattakhov, S.G., Loseva, N.L., Reznik, V.S., Konovalov, A.I., Alyab’ev, A.Yu., Gordon, L.Kh., and Zaripova, L.P., RF Patent 2158735, 2000.

  3. Fattakhov, S.G., Reznik, V.S., and Konovalov, A.I., Abstract of Papers, Sci. and Practical Conf.: “Biologically Active Substances in Ultralow Dozes. Preparations of Dual Application,” Moscow, 2007, p. 18.

  4. Karpova, G.A., Vestn. Sarat. Gosuniv., 2008, no. 3, p. 23.

  5. Alekseeva, O.M., Kim, Yu.A., Yagol’nik, E.A., Goloshchapov, A.N., Burlakova, E.B., and Fattakhov, S.G., Abstract of Papers, VIIIth All-Russian Conf. with International Participants “Chemistry and Medicine,” Ufa: Akad. Nauk of Republic Bashkortostan, Gilem, 2010, p. 98.

    Google Scholar 

  6. Sal’nikov, Yu.I., Boos, G.A., Fattakhov, S.G., Kuz’mina, N.L., and Neklyudov, V.V., Uchenye Zapiski KGU, 2009, vol. 151, no. 4, p. 29.

    Google Scholar 

  7. Sal’nikov, Yu.I., Boos, G.A., Ryzhkina, I.S., Fattakhov, S.G., Chmutova, G.A., and Zaripova, G.R., Zh. Obshch. Khim., 2009, vol. 79, no. 6, p. 323.

    Google Scholar 

  8. Roth, B. and Strelitz, J.Z., J. Org. Chem., 1969, vol. 34, no. 4, p. 821.

    Article  CAS  Google Scholar 

  9. Albert, A., Goldacre, R., and Phillips, J., J. Chem. Soc., 1948, p. 2240.

  10. Cambridgesoft — ChemBioOffice Ultra, ver. 12.0 http://cambridgesoft.com/software/chembiooffice .

  11. Beck, M.T. and Nagypál, I., Chemistry of Complex Equilibria, Moscow: Mir, 1989..

    Google Scholar 

  12. Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Analytical Chemistry Handbook), Moscow: Khimiya, 1965.

    Google Scholar 

  13. Mironov, V.E. and Isaev, I.D., Vvedenie v khimiyu vneshnesfernykh kompleksnykh soedinenii metallov v rastvorakh (Introduction to the Chemistry of Outer-Sphere Complex Compounds of Metals in Solutions), Krasnoyarsk: Krasnoyarsk Univ., 1986.

    Google Scholar 

  14. Bjerrum, J. and Skibsted, L.H., Acta Chem. Scand. (A), 1977, vol. 31, no. 8, p. 673.

    Article  CAS  Google Scholar 

  15. Manfredini, T., Pellacani, G.C., Bonamartini-Corradi, A., Battaglia, L.P., Guarini, G.G.T., Giusti, J.G., Pon, G., Willett, R.D., and West, D.X., Inorg. Chem., 1990, vol. 29, no. 12, p. 2221.

    Article  CAS  Google Scholar 

  16. Garnovskii, D.A., Garnovskii, A.D., Sadimenko, A.P., and Sigeikin, S.G., Koord. Khim., 1994, vol. 20, no. 2, p. 83.

    Google Scholar 

  17. Sharif, M.A., Aghabozorg, H., Shokrollahi, A., Kickelbick, G., Moghimi, A., and Shamsipur, M., Pol. J. Chem., 2006, vol. 80, no. 6, p. 847.

    CAS  Google Scholar 

  18. Sal’nikov, Yu.I., Glebov, A.N., and Devyatov, F.V., Poliyadernye kompleksy v rastvorakh (Polynuclear Complexes in Solutions), Kazan: Kazan Univ., 1989.

    Google Scholar 

  19. Doerfel, K., Statistics in Analytical Chemistry, Moscow: Mir, 1969.

    Google Scholar 

  20. Hartley, F.R., Burgess, S., and Alcock, R.M., Solution Equilibria, Moscow: Mir, 1983.

    Google Scholar 

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    Yu. I. Sal’nikov, G. A. Boos & V. V. Neklyudov

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    S. G. Fattakhov & M. M. Shulaeva

Authors
  1. Yu. I. Sal’nikov
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  2. G. A. Boos
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  3. V. V. Neklyudov
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  4. S. G. Fattakhov
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  5. M. M. Shulaeva
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Correspondence to Yu. I. Sal’nikov.

Additional information

Original Russian Text © Yu.I. Sal’nikov, G.A. Boos, V.V. Neklyudov, S.G. Fattakhov, M.M. Shulaeva, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 12, pp. 2046–2051.

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Sal’nikov, Y.I., Boos, G.A., Neklyudov, V.V. et al. 2,4,6-triaminopyrimidine and its associates with bis(hydroxymethyl)phosphinic acid. State in solution, protolytic, and complexing properties. Russ J Gen Chem 82, 1999–2004 (2012). https://doi.org/10.1134/S107036321212016X

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  • DOI: https://doi.org/10.1134/S107036321212016X

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