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Features of hydrolysis of phthalic acid chlorides

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Abstract

The experimentally measured rate constants of phthaloyl and terephthaloyl chlorides hydrolysis vary at the variable reagents ratio. This change obeys the Michaelis-Menten equation suggesting the intermediate formation by the reactants of the charge-transfer complex.

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Authors and Affiliations

  1. Physical Chemistry of Combustible Minerals Department, Lytvynenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79060, Ukraine

    R. G. Makitra, G. G. Midyana & Ya. M. Vasyutyn

  2. Institute of Geology and Geochemistry of Combustible Minerals, National Academy of Sciences of Ukraine, Lviv, Ukraine

    E. Ya. Pal”chykova

Authors
  1. R. G. Makitra
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  2. G. G. Midyana
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  3. E. Ya. Pal”chykova
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  4. Ya. M. Vasyutyn
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Corresponding author

Correspondence to G. G. Midyana.

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Original Russian Text © R.G. Makitra, G.G. Midyana, E.Ya. Pal”chykova, Ya.M. Vasyutyn, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 12, pp. 2021–2023.

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Makitra, R.G., Midyana, G.G., Pal”chykova, E.Y. et al. Features of hydrolysis of phthalic acid chlorides. Russ J Gen Chem 82, 1975–1977 (2012). https://doi.org/10.1134/S1070363212120110

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  • DOI: https://doi.org/10.1134/S1070363212120110

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