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Mechanism of the reaction of 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene with diethyl phosphite

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Abstract

The reaction of a stable two-coordinate phosphorus compound, 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene, with diethyl phosphite was studied in terms of the density functional theory [DFT B3PW91/6-31G(d)]. A two-step mechanism of the reaction was established.

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia

    E. A. Ishmaeva, A. Z. Alimova, Ya. A. Vereshchagina & V. I. Galkin

  2. Kazan Branch, Joint Supercomputer Center of the Russian Academy of Sciences, ul. Lobachevskogo 2/31, Kazan, 420111, Tatarstan, Russia

    D. V. Chachkov

Authors
  1. E. A. Ishmaeva
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  2. D. V. Chachkov
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  3. A. Z. Alimova
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  4. Ya. A. Vereshchagina
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  5. V. I. Galkin
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Correspondence to E. A. Ishmaeva.

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Original Russian Text © E.A. Ishmaeva, D.V. Chachkov, A.Z. Alimova, Ya.A. Vereshchagina, V.I. Galkin, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 12, pp. 1996–1998.

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Ishmaeva, E.A., Chachkov, D.V., Alimova, A.Z. et al. Mechanism of the reaction of 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene with diethyl phosphite. Russ J Gen Chem 82, 1951–1953 (2012). https://doi.org/10.1134/S1070363212120079

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  • DOI: https://doi.org/10.1134/S1070363212120079

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