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Synthesis of the unsaturated diamines by the Stevens rearrangement of 4-diethylaminobutyn-2-yl-containing ammonium salts

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Abstract

Ammonium salts containing 4-diethylaminobutyn-2-yl and 2-alkenyl groups undergo the Stevens 3,2-rearrangement under the action of potassium hydroxide in anhydrous benzene to form the unsaturated diamines.

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Authors and Affiliations

  1. Institute of Organic Chemistry of Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, 26 Azatutyan av., Yerevan, 0014, Armenia

    M. O. Manukyan, K. S. Barseghyan & A. Kh. Gyulnazaryan

  2. Abovyan Armenian State Pedagogical University, Yerevan, Armenia

    M. O. Manukyan & A. V. Babakhanyan

  3. Molecular Structure Research Center of the Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, Yerevan, Armenia

    A. A. Shahkhatuni

Authors
  1. M. O. Manukyan
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  2. K. S. Barseghyan
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  3. A. V. Babakhanyan
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  4. A. A. Shahkhatuni
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  5. A. Kh. Gyulnazaryan
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Correspondence to M. O. Manukyan.

Additional information

Original Russian Text © M.O. Manukyan, K.S. Barseghyan, A.V. Babakhanyan, A.A. Shahkhatuni, A.Kh. Gyulnazaryan, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 11, pp. 1807–1809.

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Manukyan, M.O., Barseghyan, K.S., Babakhanyan, A.V. et al. Synthesis of the unsaturated diamines by the Stevens rearrangement of 4-diethylaminobutyn-2-yl-containing ammonium salts. Russ J Gen Chem 82, 1798–1800 (2012). https://doi.org/10.1134/S1070363212110096

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  • DOI: https://doi.org/10.1134/S1070363212110096

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